1 Ocak 2014 Dergi makalesi Açık Erişim

Kalay, Erbay; Kilic, Hamdullah; Catir, Mustafa; Cakici, Murat; Kazaz, Cavit

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{
  "@context": "https://schema.org/", 
  "@id": 64515, 
  "@type": "ScholarlyArticle", 
  "creator": [
    {
      "@type": "Person", 
      "affiliation": "Ataturk Univ, Dept Chem, Fac Sci, TR-25240 Erzurum, Turkey", 
      "name": "Kalay, Erbay"
    }, 
    {
      "@type": "Person", 
      "affiliation": "Ataturk Univ, Dept Chem, Fac Sci, TR-25240 Erzurum, Turkey", 
      "name": "Kilic, Hamdullah"
    }, 
    {
      "@type": "Person", 
      "affiliation": "Erzincan Univ, Fac Arts & Sci, Dept Chem, TR-24100 Erzincan, Turkey", 
      "name": "Catir, Mustafa"
    }, 
    {
      "@type": "Person", 
      "affiliation": "Ataturk Univ, Dept Chem, Fac Sci, TR-25240 Erzurum, Turkey", 
      "name": "Cakici, Murat"
    }, 
    {
      "@type": "Person", 
      "affiliation": "Ataturk Univ, Dept Chem, Fac Sci, TR-25240 Erzurum, Turkey", 
      "name": "Kazaz, Cavit"
    }
  ], 
  "datePublished": "2014-01-01", 
  "description": "A novel method for the production of singlet oxygen from H2O2 was developed. A combination of iodoarene (ArI), methyltrioxorhenium (MTO), and H2O2 in the presence of pyridine as the co-catalyst efficiently produced singlet molecular oxygen (O-1(2)) under biphasic conditions. The existence of O-1(2) was demonstrated by trapping experiments with aromatic dienes, 1,3-cyclodienes, and alkenes. The mechanism of O-1(2) production from the iodoarene/MTO/35 % H2O2 system and the reaction scope was also discussed.", 
  "headline": "Generation of singlet oxygen (O-1(2)) from hydrogen peroxide decomposition by in situ generated hypervalent iodoarene reagents", 
  "identifier": 64515, 
  "image": "https://aperta.ulakbim.gov.tr/static/img/logo/aperta_logo_with_icon.svg", 
  "license": "http://www.opendefinition.org/licenses/cc-by", 
  "name": "Generation of singlet oxygen (O-1(2)) from hydrogen peroxide decomposition by in situ generated hypervalent iodoarene reagents", 
  "url": "https://aperta.ulakbim.gov.tr/record/64515"
}