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Synthesis of amino-cyclobutanes via [2+2] cycloadditions involving keteniminium intermediates

Kolleth, Amandine; Lumbroso, Alexandre; Tanriver, Gamze; Catak, Saron; Sulzer-Mosse, Sarah; De Mesmaeker, Alain


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  <identifier identifierType="URL">https://aperta.ulakbim.gov.tr/record/54513</identifier>
  <creators>
    <creator>
      <creatorName>Kolleth, Amandine</creatorName>
      <givenName>Amandine</givenName>
      <familyName>Kolleth</familyName>
      <affiliation>Syngenta Crop Protect AG, Crop Protect Res, Res Chem, Schaffhauserstr 101, CH-4332 Basel, Switzerland</affiliation>
    </creator>
    <creator>
      <creatorName>Lumbroso, Alexandre</creatorName>
      <givenName>Alexandre</givenName>
      <familyName>Lumbroso</familyName>
      <affiliation>Syngenta Crop Protect AG, Crop Protect Res, Res Chem, Schaffhauserstr 101, CH-4332 Basel, Switzerland</affiliation>
    </creator>
    <creator>
      <creatorName>Tanriver, Gamze</creatorName>
      <givenName>Gamze</givenName>
      <familyName>Tanriver</familyName>
      <affiliation>Bogazici Univ, Dept Chem, TR-34342 Istanbul, Turkey</affiliation>
    </creator>
    <creator>
      <creatorName>Catak, Saron</creatorName>
      <givenName>Saron</givenName>
      <familyName>Catak</familyName>
      <affiliation>Bogazici Univ, Dept Chem, TR-34342 Istanbul, Turkey</affiliation>
    </creator>
    <creator>
      <creatorName>Sulzer-Mosse, Sarah</creatorName>
      <givenName>Sarah</givenName>
      <familyName>Sulzer-Mosse</familyName>
      <affiliation>Syngenta Crop Protect AG, Crop Protect Res, Res Chem, Schaffhauserstr 101, CH-4332 Basel, Switzerland</affiliation>
    </creator>
    <creator>
      <creatorName>De Mesmaeker, Alain</creatorName>
      <givenName>Alain</givenName>
      <familyName>De Mesmaeker</familyName>
      <affiliation>Syngenta Crop Protect AG, Crop Protect Res, Res Chem, Schaffhauserstr 101, CH-4332 Basel, Switzerland</affiliation>
    </creator>
  </creators>
  <titles>
    <title>Synthesis Of Amino-Cyclobutanes Via [2+2] Cycloadditions Involving Keteniminium Intermediates</title>
  </titles>
  <publisher>Aperta</publisher>
  <publicationYear>2016</publicationYear>
  <dates>
    <date dateType="Issued">2016-01-01</date>
  </dates>
  <resourceType resourceTypeGeneral="Text">Journal article</resourceType>
  <alternateIdentifiers>
    <alternateIdentifier alternateIdentifierType="url">https://aperta.ulakbim.gov.tr/record/54513</alternateIdentifier>
  </alternateIdentifiers>
  <relatedIdentifiers>
    <relatedIdentifier relatedIdentifierType="DOI" relationType="IsIdenticalTo">10.1016/j.tetlet.2016.04.092</relatedIdentifier>
  </relatedIdentifiers>
  <rightsList>
    <rights rightsURI="http://www.opendefinition.org/licenses/cc-by">Creative Commons Attribution</rights>
    <rights rightsURI="info:eu-repo/semantics/openAccess">Open Access</rights>
  </rightsList>
  <descriptions>
    <description descriptionType="Abstract">We describe an efficient method for the synthesis of aminocyclobutanes via a [2 + 2] cycloaddition between a keteniminium salt and an alkene, followed by a reduction step. The use of easily removable N-allyl moieties as protecting groups increases the potential of this method to access, in a few steps, highly functionalized cyclobutaneamine-containing building blocks. Moreover, DFT calculations verify the compatibility of N-allyl and N-propargyl keteniminiums in [2 + 2] cycloaddition reactions. (C) 2016 Elsevier Ltd. All rights reserved.</description>
  </descriptions>
</resource>
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