1 Ocak 2017 Dergi makalesi Açık Erişim

Kreutzer, Johannes; Kaya, Kerem; Yagci, Yusuf

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  <dc:creator>Kreutzer, Johannes</dc:creator>
  <dc:creator>Kaya, Kerem</dc:creator>
  <dc:creator>Yagci, Yusuf</dc:creator>
  <dc:date>2017-01-01</dc:date>
  <dc:description>A novel kind of low migration one-component Type II photoinitiators was synthesized by Schiff base reaction of thioxanthone aldehyde and amine functional poly(propylene oxide) (PPO) precursors with two different molecular weights. The final initiators (TX-PPO) were characterized in detail by spectral analysis and DFT theoretical calculations. The molecular weight of the PPO directly effects the solubility of the initiator in monomers. The one-component photo initiating nature of the initiators was demonstrated by photobleaching and photo polymerization of several vinyl monomers in the absence of a hydrogen donor such as triethylamine. Leaching studies on the photocured polymer films show only negligible migration of the photoinitiator.</dc:description>
  <dc:identifier>https://aperta.ulakbim.gov.trrecord/51725</dc:identifier>
  <dc:identifier>oai:zenodo.org:51725</dc:identifier>
  <dc:rights>info:eu-repo/semantics/openAccess</dc:rights>
  <dc:rights>http://www.opendefinition.org/licenses/cc-by</dc:rights>
  <dc:source>EUROPEAN POLYMER JOURNAL 95 71-81</dc:source>
  <dc:title>Poly(propylene oxide)-thioxanthone as one-component Type II polymeric photoinitiator for free radical polymerization with low migration behavior</dc:title>
  <dc:type>info:eu-repo/semantics/article</dc:type>
  <dc:type>publication-article</dc:type>
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