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Poly(propylene oxide)-thioxanthone as one-component Type II polymeric photoinitiator for free radical polymerization with low migration behavior

Kreutzer, Johannes; Kaya, Kerem; Yagci, Yusuf


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{
  "@context": "https://schema.org/", 
  "@id": 51725, 
  "@type": "ScholarlyArticle", 
  "creator": [
    {
      "@type": "Person", 
      "affiliation": "Istanbul Tech Univ, Dept Chem, TR-34469 Istanbul, Turkey", 
      "name": "Kreutzer, Johannes"
    }, 
    {
      "@type": "Person", 
      "affiliation": "Istanbul Tech Univ, Dept Chem, TR-34469 Istanbul, Turkey", 
      "name": "Kaya, Kerem"
    }, 
    {
      "@type": "Person", 
      "affiliation": "Istanbul Tech Univ, Dept Chem, TR-34469 Istanbul, Turkey", 
      "name": "Yagci, Yusuf"
    }
  ], 
  "datePublished": "2017-01-01", 
  "description": "A novel kind of low migration one-component Type II photoinitiators was synthesized by Schiff base reaction of thioxanthone aldehyde and amine functional poly(propylene oxide) (PPO) precursors with two different molecular weights. The final initiators (TX-PPO) were characterized in detail by spectral analysis and DFT theoretical calculations. The molecular weight of the PPO directly effects the solubility of the initiator in monomers. The one-component photo initiating nature of the initiators was demonstrated by photobleaching and photo polymerization of several vinyl monomers in the absence of a hydrogen donor such as triethylamine. Leaching studies on the photocured polymer films show only negligible migration of the photoinitiator.", 
  "headline": "Poly(propylene oxide)-thioxanthone as one-component Type II polymeric photoinitiator for free radical polymerization with low migration behavior", 
  "identifier": 51725, 
  "image": "https://aperta.ulakbim.gov.tr/static/img/logo/aperta_logo_with_icon.svg", 
  "license": "http://www.opendefinition.org/licenses/cc-by", 
  "name": "Poly(propylene oxide)-thioxanthone as one-component Type II polymeric photoinitiator for free radical polymerization with low migration behavior", 
  "url": "https://aperta.ulakbim.gov.tr/record/51725"
}
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