Dergi makalesi Açık Erişim
Kreutzer, Johannes; Kaya, Kerem; Yagci, Yusuf
{ "@context": "https://schema.org/", "@id": 51725, "@type": "ScholarlyArticle", "creator": [ { "@type": "Person", "affiliation": "Istanbul Tech Univ, Dept Chem, TR-34469 Istanbul, Turkey", "name": "Kreutzer, Johannes" }, { "@type": "Person", "affiliation": "Istanbul Tech Univ, Dept Chem, TR-34469 Istanbul, Turkey", "name": "Kaya, Kerem" }, { "@type": "Person", "affiliation": "Istanbul Tech Univ, Dept Chem, TR-34469 Istanbul, Turkey", "name": "Yagci, Yusuf" } ], "datePublished": "2017-01-01", "description": "A novel kind of low migration one-component Type II photoinitiators was synthesized by Schiff base reaction of thioxanthone aldehyde and amine functional poly(propylene oxide) (PPO) precursors with two different molecular weights. The final initiators (TX-PPO) were characterized in detail by spectral analysis and DFT theoretical calculations. The molecular weight of the PPO directly effects the solubility of the initiator in monomers. The one-component photo initiating nature of the initiators was demonstrated by photobleaching and photo polymerization of several vinyl monomers in the absence of a hydrogen donor such as triethylamine. Leaching studies on the photocured polymer films show only negligible migration of the photoinitiator.", "headline": "Poly(propylene oxide)-thioxanthone as one-component Type II polymeric photoinitiator for free radical polymerization with low migration behavior", "identifier": 51725, "image": "https://aperta.ulakbim.gov.tr/static/img/logo/aperta_logo_with_icon.svg", "license": "http://www.opendefinition.org/licenses/cc-by", "name": "Poly(propylene oxide)-thioxanthone as one-component Type II polymeric photoinitiator for free radical polymerization with low migration behavior", "url": "https://aperta.ulakbim.gov.tr/record/51725" }
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