1 Ocak 2017 Dergi makalesi Açık Erişim

Kreutzer, Johannes; Kaya, Kerem; Yagci, Yusuf

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  <identifier identifierType="URL">https://aperta.ulakbim.gov.tr/record/51725</identifier>
  <creators>
    <creator>
      <creatorName>Kreutzer, Johannes</creatorName>
      <givenName>Johannes</givenName>
      <familyName>Kreutzer</familyName>
      <affiliation>Istanbul Tech Univ, Dept Chem, TR-34469 Istanbul, Turkey</affiliation>
    </creator>
    <creator>
      <creatorName>Kaya, Kerem</creatorName>
      <givenName>Kerem</givenName>
      <familyName>Kaya</familyName>
      <affiliation>Istanbul Tech Univ, Dept Chem, TR-34469 Istanbul, Turkey</affiliation>
    </creator>
    <creator>
      <creatorName>Yagci, Yusuf</creatorName>
      <givenName>Yusuf</givenName>
      <familyName>Yagci</familyName>
      <affiliation>Istanbul Tech Univ, Dept Chem, TR-34469 Istanbul, Turkey</affiliation>
    </creator>
  </creators>
  <titles>
    <title>Poly(Propylene Oxide)-Thioxanthone As One-Component Type Ii Polymeric Photoinitiator For Free Radical Polymerization With Low Migration Behavior</title>
  </titles>
  <publisher>Aperta</publisher>
  <publicationYear>2017</publicationYear>
  <dates>
    <date dateType="Issued">2017-01-01</date>
  </dates>
  <resourceType resourceTypeGeneral="Text">Journal article</resourceType>
  <alternateIdentifiers>
    <alternateIdentifier alternateIdentifierType="url">https://aperta.ulakbim.gov.tr/record/51725</alternateIdentifier>
  </alternateIdentifiers>
  <relatedIdentifiers>
    <relatedIdentifier relatedIdentifierType="DOI" relationType="IsIdenticalTo">10.1016/j.eurpolymj.2017.07.030</relatedIdentifier>
  </relatedIdentifiers>
  <rightsList>
    <rights rightsURI="http://www.opendefinition.org/licenses/cc-by">Creative Commons Attribution</rights>
    <rights rightsURI="info:eu-repo/semantics/openAccess">Open Access</rights>
  </rightsList>
  <descriptions>
    <description descriptionType="Abstract">A novel kind of low migration one-component Type II photoinitiators was synthesized by Schiff base reaction of thioxanthone aldehyde and amine functional poly(propylene oxide) (PPO) precursors with two different molecular weights. The final initiators (TX-PPO) were characterized in detail by spectral analysis and DFT theoretical calculations. The molecular weight of the PPO directly effects the solubility of the initiator in monomers. The one-component photo initiating nature of the initiators was demonstrated by photobleaching and photo polymerization of several vinyl monomers in the absence of a hydrogen donor such as triethylamine. Leaching studies on the photocured polymer films show only negligible migration of the photoinitiator.</description>
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