1 Ocak 2017 Dergi makalesi Açık Erişim

Kreutzer, Johannes; Kaya, Kerem; Yagci, Yusuf

Citation Style Language JSON

{
  "DOI": "10.1016/j.eurpolymj.2017.07.030", 
  "abstract": "A novel kind of low migration one-component Type II photoinitiators was synthesized by Schiff base reaction of thioxanthone aldehyde and amine functional poly(propylene oxide) (PPO) precursors with two different molecular weights. The final initiators (TX-PPO) were characterized in detail by spectral analysis and DFT theoretical calculations. The molecular weight of the PPO directly effects the solubility of the initiator in monomers. The one-component photo initiating nature of the initiators was demonstrated by photobleaching and photo polymerization of several vinyl monomers in the absence of a hydrogen donor such as triethylamine. Leaching studies on the photocured polymer films show only negligible migration of the photoinitiator.", 
  "author": [
    {
      "family": "Kreutzer", 
      "given": " Johannes"
    }, 
    {
      "family": "Kaya", 
      "given": " Kerem"
    }, 
    {
      "family": "Yagci", 
      "given": " Yusuf"
    }
  ], 
  "container_title": "EUROPEAN POLYMER JOURNAL", 
  "id": "51725", 
  "issued": {
    "date-parts": [
      [
        2017, 
        1, 
        1
      ]
    ]
  }, 
  "page": "71-81", 
  "title": "Poly(propylene oxide)-thioxanthone as one-component Type II polymeric photoinitiator for free radical polymerization with low migration behavior", 
  "type": "article-journal", 
  "volume": "95"
}