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Synthesis and characterization of functional copolymer/organo-silicate nanoarchitectures through interlamellar complex-radical (co)terpolymerization

Soeylemez, E.; Caylak, N.; Rzayev, Z. M. O.


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<oai_dc:dc xmlns:dc="http://purl.org/dc/elements/1.1/" xmlns:oai_dc="http://www.openarchives.org/OAI/2.0/oai_dc/" xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance" xsi:schemaLocation="http://www.openarchives.org/OAI/2.0/oai_dc/ http://www.openarchives.org/OAI/2.0/oai_dc.xsd">
  <dc:creator>Soeylemez, E.</dc:creator>
  <dc:creator>Caylak, N.</dc:creator>
  <dc:creator>Rzayev, Z. M. O.</dc:creator>
  <dc:date>2008-01-01</dc:date>
  <dc:description>The functional copolymers, having a combination of rigid/flexible linkages and an ability of complex-formation with interlayered surface of organo-silicate, and their nanocomposites have been synthesized by interlamellar complex-radical (co)terpolymerization of intercalated monomer complexes of maleic anhydride (MA) and itaconic acid (IA) with dimethyl dodecylamine surface modified montmorillonite (organo-MMT) (MA. DMDA-MMT and IA...DMDA-MMT) n-butyl methacrylate (BMA) and/or BMA/styrene monomer mixtures. The results of nanocomposite structure-composition-property relationship studies indicate that interlamellar complex-formation between anhydride/acid units and surface alkyl amine and rigid/flexible linkage balance in polymer chains are important factors providing the effective intercalation/exfoliation of the polymer chains into the silicate galleries, the formation of nanostructural hybrids with higher thermal stability, dynamic mechanical behaviour and well dispersed morphology.</dc:description>
  <dc:identifier>https://aperta.ulakbim.gov.trrecord/42551</dc:identifier>
  <dc:identifier>oai:zenodo.org:42551</dc:identifier>
  <dc:rights>info:eu-repo/semantics/openAccess</dc:rights>
  <dc:rights>http://www.opendefinition.org/licenses/cc-by</dc:rights>
  <dc:source>EXPRESS POLYMER LETTERS 2(9) 639-654</dc:source>
  <dc:title>Synthesis and characterization of functional copolymer/organo-silicate nanoarchitectures through interlamellar complex-radical (co)terpolymerization</dc:title>
  <dc:type>info:eu-repo/semantics/article</dc:type>
  <dc:type>publication-article</dc:type>
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