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Synthesis and characterization of functional copolymer/organo-silicate nanoarchitectures through interlamellar complex-radical (co)terpolymerization

Soeylemez, E.; Caylak, N.; Rzayev, Z. M. O.


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{
  "DOI": "10.3144/expresspolymlett.2008.77", 
  "abstract": "The functional copolymers, having a combination of rigid/flexible linkages and an ability of complex-formation with interlayered surface of organo-silicate, and their nanocomposites have been synthesized by interlamellar complex-radical (co)terpolymerization of intercalated monomer complexes of maleic anhydride (MA) and itaconic acid (IA) with dimethyl dodecylamine surface modified montmorillonite (organo-MMT) (MA. DMDA-MMT and IA...DMDA-MMT) n-butyl methacrylate (BMA) and/or BMA/styrene monomer mixtures. The results of nanocomposite structure-composition-property relationship studies indicate that interlamellar complex-formation between anhydride/acid units and surface alkyl amine and rigid/flexible linkage balance in polymer chains are important factors providing the effective intercalation/exfoliation of the polymer chains into the silicate galleries, the formation of nanostructural hybrids with higher thermal stability, dynamic mechanical behaviour and well dispersed morphology.", 
  "author": [
    {
      "family": "Soeylemez", 
      "given": " E."
    }, 
    {
      "family": "Caylak", 
      "given": " N."
    }, 
    {
      "family": "Rzayev", 
      "given": " Z. M. O."
    }
  ], 
  "container_title": "EXPRESS POLYMER LETTERS", 
  "id": "42551", 
  "issue": "9", 
  "issued": {
    "date-parts": [
      [
        2008, 
        1, 
        1
      ]
    ]
  }, 
  "page": "639-654", 
  "title": "Synthesis and characterization of functional copolymer/organo-silicate nanoarchitectures through interlamellar complex-radical (co)terpolymerization", 
  "type": "article-journal", 
  "volume": "2"
}
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