Dergi makalesi Açık Erişim
Soeylemez, E.; Caylak, N.; Rzayev, Z. M. O.
{
"DOI": "10.3144/expresspolymlett.2008.77",
"abstract": "The functional copolymers, having a combination of rigid/flexible linkages and an ability of complex-formation with interlayered surface of organo-silicate, and their nanocomposites have been synthesized by interlamellar complex-radical (co)terpolymerization of intercalated monomer complexes of maleic anhydride (MA) and itaconic acid (IA) with dimethyl dodecylamine surface modified montmorillonite (organo-MMT) (MA. DMDA-MMT and IA...DMDA-MMT) n-butyl methacrylate (BMA) and/or BMA/styrene monomer mixtures. The results of nanocomposite structure-composition-property relationship studies indicate that interlamellar complex-formation between anhydride/acid units and surface alkyl amine and rigid/flexible linkage balance in polymer chains are important factors providing the effective intercalation/exfoliation of the polymer chains into the silicate galleries, the formation of nanostructural hybrids with higher thermal stability, dynamic mechanical behaviour and well dispersed morphology.",
"author": [
{
"family": "Soeylemez",
"given": " E."
},
{
"family": "Caylak",
"given": " N."
},
{
"family": "Rzayev",
"given": " Z. M. O."
}
],
"container_title": "EXPRESS POLYMER LETTERS",
"id": "42551",
"issue": "9",
"issued": {
"date-parts": [
[
2008,
1,
1
]
]
},
"page": "639-654",
"title": "Synthesis and characterization of functional copolymer/organo-silicate nanoarchitectures through interlamellar complex-radical (co)terpolymerization",
"type": "article-journal",
"volume": "2"
}
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