1 Ocak 2008 Dergi makalesi Açık Erişim

Soeylemez, E.; Caylak, N.; Rzayev, Z. M. O.

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  <identifier identifierType="URL">https://aperta.ulakbim.gov.tr/record/42551</identifier>
  <creators>
    <creator>
      <creatorName>Soeylemez, E.</creatorName>
      <givenName>E.</givenName>
      <familyName>Soeylemez</familyName>
      <affiliation>Hacettepe Univ, Fac Engn, Dept Chem Engn, TR-06800 Ankara, Turkey</affiliation>
    </creator>
    <creator>
      <creatorName>Caylak, N.</creatorName>
      <givenName>N.</givenName>
      <familyName>Caylak</familyName>
      <affiliation>Sakarya Univ, Fac Art &amp; Sci, Dept Phys, TR-54187 Sakarya, Turkey</affiliation>
    </creator>
    <creator>
      <creatorName>Rzayev, Z. M. O.</creatorName>
      <givenName>Z. M. O.</givenName>
      <familyName>Rzayev</familyName>
      <affiliation>Hacettepe Univ, Fac Engn, Dept Chem Engn, TR-06800 Ankara, Turkey</affiliation>
    </creator>
  </creators>
  <titles>
    <title>Synthesis And Characterization Of Functional Copolymer/Organo-Silicate Nanoarchitectures Through Interlamellar Complex-Radical (Co)Terpolymerization</title>
  </titles>
  <publisher>Aperta</publisher>
  <publicationYear>2008</publicationYear>
  <dates>
    <date dateType="Issued">2008-01-01</date>
  </dates>
  <resourceType resourceTypeGeneral="Text">Journal article</resourceType>
  <alternateIdentifiers>
    <alternateIdentifier alternateIdentifierType="url">https://aperta.ulakbim.gov.tr/record/42551</alternateIdentifier>
  </alternateIdentifiers>
  <relatedIdentifiers>
    <relatedIdentifier relatedIdentifierType="DOI" relationType="IsIdenticalTo">10.3144/expresspolymlett.2008.77</relatedIdentifier>
  </relatedIdentifiers>
  <rightsList>
    <rights rightsURI="http://www.opendefinition.org/licenses/cc-by">Creative Commons Attribution</rights>
    <rights rightsURI="info:eu-repo/semantics/openAccess">Open Access</rights>
  </rightsList>
  <descriptions>
    <description descriptionType="Abstract">The functional copolymers, having a combination of rigid/flexible linkages and an ability of complex-formation with interlayered surface of organo-silicate, and their nanocomposites have been synthesized by interlamellar complex-radical (co)terpolymerization of intercalated monomer complexes of maleic anhydride (MA) and itaconic acid (IA) with dimethyl dodecylamine surface modified montmorillonite (organo-MMT) (MA. DMDA-MMT and IA...DMDA-MMT) n-butyl methacrylate (BMA) and/or BMA/styrene monomer mixtures. The results of nanocomposite structure-composition-property relationship studies indicate that interlamellar complex-formation between anhydride/acid units and surface alkyl amine and rigid/flexible linkage balance in polymer chains are important factors providing the effective intercalation/exfoliation of the polymer chains into the silicate galleries, the formation of nanostructural hybrids with higher thermal stability, dynamic mechanical behaviour and well dispersed morphology.</description>
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