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Synthesis and characterization of functional copolymer/organo-silicate nanoarchitectures through interlamellar complex-radical (co)terpolymerization

Soeylemez, E.; Caylak, N.; Rzayev, Z. M. O.


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        "affiliation": "Hacettepe Univ, Fac Engn, Dept Chem Engn, TR-06800 Ankara, Turkey", 
        "name": "Soeylemez, E."
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        "affiliation": "Sakarya Univ, Fac Art & Sci, Dept Phys, TR-54187 Sakarya, Turkey", 
        "name": "Caylak, N."
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        "affiliation": "Hacettepe Univ, Fac Engn, Dept Chem Engn, TR-06800 Ankara, Turkey", 
        "name": "Rzayev, Z. M. O."
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    "description": "The functional copolymers, having a combination of rigid/flexible linkages and an ability of complex-formation with interlayered surface of organo-silicate, and their nanocomposites have been synthesized by interlamellar complex-radical (co)terpolymerization of intercalated monomer complexes of maleic anhydride (MA) and itaconic acid (IA) with dimethyl dodecylamine surface modified montmorillonite (organo-MMT) (MA. DMDA-MMT and IA...DMDA-MMT) n-butyl methacrylate (BMA) and/or BMA/styrene monomer mixtures. The results of nanocomposite structure-composition-property relationship studies indicate that interlamellar complex-formation between anhydride/acid units and surface alkyl amine and rigid/flexible linkage balance in polymer chains are important factors providing the effective intercalation/exfoliation of the polymer chains into the silicate galleries, the formation of nanostructural hybrids with higher thermal stability, dynamic mechanical behaviour and well dispersed morphology.", 
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