1 Ocak 2008 Dergi makalesi Açık Erişim

Aslan, F.; Arslan, M.

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  <dc:creator>Aslan, F.</dc:creator>
  <dc:creator>Arslan, M.</dc:creator>
  <dc:date>2008-01-01</dc:date>
  <dc:description>The reaction between phenylmagnesium bromide and hexachlorocyclotriphophazene (N3P3Cl6) ( 1) was reinvestigated for the synthesis of hexaphenylcyclotriphosphazene (N3P3Ph6) ( 2) in high yield. The reaction is complete within two weeks at room temperature using toluene as solvent. When the reactants (PhMgBr and N3P3Cl6) were employed in a 6: 1, 36: 1 and 72: 1 molar ratio, compound 2 was obtained in 2.6%, 14%, and 33.4% yield, respectively. The formation of N3P3Cl6 ( 2) during the reaction was followed by thin-layer chromatography. Compound 2 was characterized by elemental analysis, IR, UV-VIS, H-1, C-13, and P-31 NMR spectroscopy as well as by mass spectrometry.</dc:description>
  <dc:identifier>https://aperta.ulakbim.gov.trrecord/41795</dc:identifier>
  <dc:identifier>oai:zenodo.org:41795</dc:identifier>
  <dc:rights>info:eu-repo/semantics/openAccess</dc:rights>
  <dc:rights>http://www.opendefinition.org/licenses/cc-by</dc:rights>
  <dc:source>PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS 183(11) 2875-2881</dc:source>
  <dc:title>The Synthesis of Hexaphenylcyclotriphosphazene in Improved Yield</dc:title>
  <dc:type>info:eu-repo/semantics/article</dc:type>
  <dc:type>publication-article</dc:type>
</oai_dc:dc>