1 Ocak 2008 Dergi makalesi Açık Erişim

Aslan, F.; Arslan, M.

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  <identifier identifierType="URL">https://aperta.ulakbim.gov.tr/record/41795</identifier>
  <creators>
    <creator>
      <creatorName>Aslan, F.</creatorName>
      <givenName>F.</givenName>
      <familyName>Aslan</familyName>
      <affiliation>Harran Univ, Dept Chem, TR-63100 Sanliurfa, Turkey</affiliation>
    </creator>
    <creator>
      <creatorName>Arslan, M.</creatorName>
      <givenName>M.</givenName>
      <familyName>Arslan</familyName>
      <affiliation>Firat Univ, Dept Chem, TR-23169 Elazig, Turkey</affiliation>
    </creator>
  </creators>
  <titles>
    <title>The Synthesis Of Hexaphenylcyclotriphosphazene In Improved Yield</title>
  </titles>
  <publisher>Aperta</publisher>
  <publicationYear>2008</publicationYear>
  <dates>
    <date dateType="Issued">2008-01-01</date>
  </dates>
  <resourceType resourceTypeGeneral="Text">Journal article</resourceType>
  <alternateIdentifiers>
    <alternateIdentifier alternateIdentifierType="url">https://aperta.ulakbim.gov.tr/record/41795</alternateIdentifier>
  </alternateIdentifiers>
  <relatedIdentifiers>
    <relatedIdentifier relatedIdentifierType="DOI" relationType="IsIdenticalTo">10.1080/10426500802023915</relatedIdentifier>
  </relatedIdentifiers>
  <rightsList>
    <rights rightsURI="http://www.opendefinition.org/licenses/cc-by">Creative Commons Attribution</rights>
    <rights rightsURI="info:eu-repo/semantics/openAccess">Open Access</rights>
  </rightsList>
  <descriptions>
    <description descriptionType="Abstract">The reaction between phenylmagnesium bromide and hexachlorocyclotriphophazene (N3P3Cl6) ( 1) was reinvestigated for the synthesis of hexaphenylcyclotriphosphazene (N3P3Ph6) ( 2) in high yield. The reaction is complete within two weeks at room temperature using toluene as solvent. When the reactants (PhMgBr and N3P3Cl6) were employed in a 6: 1, 36: 1 and 72: 1 molar ratio, compound 2 was obtained in 2.6%, 14%, and 33.4% yield, respectively. The formation of N3P3Cl6 ( 2) during the reaction was followed by thin-layer chromatography. Compound 2 was characterized by elemental analysis, IR, UV-VIS, H-1, C-13, and P-31 NMR spectroscopy as well as by mass spectrometry.</description>
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