1 Ocak 2008 Dergi makalesi Açık Erişim

Aslan, F.; Arslan, M.

Citation Style Language JSON

{
  "DOI": "10.1080/10426500802023915", 
  "abstract": "The reaction between phenylmagnesium bromide and hexachlorocyclotriphophazene (N3P3Cl6) ( 1) was reinvestigated for the synthesis of hexaphenylcyclotriphosphazene (N3P3Ph6) ( 2) in high yield. The reaction is complete within two weeks at room temperature using toluene as solvent. When the reactants (PhMgBr and N3P3Cl6) were employed in a 6: 1, 36: 1 and 72: 1 molar ratio, compound 2 was obtained in 2.6%, 14%, and 33.4% yield, respectively. The formation of N3P3Cl6 ( 2) during the reaction was followed by thin-layer chromatography. Compound 2 was characterized by elemental analysis, IR, UV-VIS, H-1, C-13, and P-31 NMR spectroscopy as well as by mass spectrometry.", 
  "author": [
    {
      "family": "Aslan", 
      "given": " F."
    }, 
    {
      "family": "Arslan", 
      "given": " M."
    }
  ], 
  "container_title": "PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS", 
  "id": "41795", 
  "issue": "11", 
  "issued": {
    "date-parts": [
      [
        2008, 
        1, 
        1
      ]
    ]
  }, 
  "page": "2875-2881", 
  "title": "The Synthesis of Hexaphenylcyclotriphosphazene in Improved Yield", 
  "type": "article-journal", 
  "volume": "183"
}