1 Ocak 2008 Dergi makalesi Açık Erişim

Aslan, F.; Arslan, M.

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{
  "@context": "https://schema.org/", 
  "@id": 41795, 
  "@type": "ScholarlyArticle", 
  "creator": [
    {
      "@type": "Person", 
      "affiliation": "Harran Univ, Dept Chem, TR-63100 Sanliurfa, Turkey", 
      "name": "Aslan, F."
    }, 
    {
      "@type": "Person", 
      "affiliation": "Firat Univ, Dept Chem, TR-23169 Elazig, Turkey", 
      "name": "Arslan, M."
    }
  ], 
  "datePublished": "2008-01-01", 
  "description": "The reaction between phenylmagnesium bromide and hexachlorocyclotriphophazene (N3P3Cl6) ( 1) was reinvestigated for the synthesis of hexaphenylcyclotriphosphazene (N3P3Ph6) ( 2) in high yield. The reaction is complete within two weeks at room temperature using toluene as solvent. When the reactants (PhMgBr and N3P3Cl6) were employed in a 6: 1, 36: 1 and 72: 1 molar ratio, compound 2 was obtained in 2.6%, 14%, and 33.4% yield, respectively. The formation of N3P3Cl6 ( 2) during the reaction was followed by thin-layer chromatography. Compound 2 was characterized by elemental analysis, IR, UV-VIS, H-1, C-13, and P-31 NMR spectroscopy as well as by mass spectrometry.", 
  "headline": "The Synthesis of Hexaphenylcyclotriphosphazene in Improved Yield", 
  "identifier": 41795, 
  "image": "https://aperta.ulakbim.gov.tr/static/img/logo/aperta_logo_with_icon.svg", 
  "license": "http://www.opendefinition.org/licenses/cc-by", 
  "name": "The Synthesis of Hexaphenylcyclotriphosphazene in Improved Yield", 
  "url": "https://aperta.ulakbim.gov.tr/record/41795"
}