1 Ocak 2009 Dergi makalesi Açık Erişim

Colak, Alper Tolga; Irez, Gazi; Mutlu, Hasene; Hokelek, Tuncer; Caylak, Nagihan

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  <dc:creator>Colak, Alper Tolga</dc:creator>
  <dc:creator>Irez, Gazi</dc:creator>
  <dc:creator>Mutlu, Hasene</dc:creator>
  <dc:creator>Hokelek, Tuncer</dc:creator>
  <dc:creator>Caylak, Nagihan</dc:creator>
  <dc:date>2009-01-01</dc:date>
  <dc:description>A cobalt(III) complex [Co(L)2]Cl PPO H2O (1) (HL = 1-(2-aminobenzylimino)-1-phenyl-propan-2-one oxime, PPO = 1-phenyl-1,2-propanedione-2-oxime) has been synthesized and characterized by elemental analyses, spectral, thermal, magnetic and molar conductance measurements and single crystal X-ray diffraction. It crystallizes in the monoclinic crystal system, space group P21/c. Complex 1 consists of one uncoordinated water, one 1-phenyl-1,2-propanedione-2-oxime molecule, one bis[1-(2-aminobenzylimino)-1-phenyl-propan-2-one oxime]cobalt(III) cation and one uncoordinated chloride. The coordination geometry around Co is slightly distorted octahedral, completed with six nitrogens of two L- ligands. The oxime moieties have E configurations. In the crystal structure, intramolecular O-HCl and N-HO and intermolecular N-HO, O-HCl and N-HCl hydrogen bonds link the molecules into chains parallel to the c axis; hydrogen-bonded PPO molecules fill the spaces between the chains and stabilization of the structure.</dc:description>
  <dc:identifier>https://aperta.ulakbim.gov.trrecord/39553</dc:identifier>
  <dc:identifier>oai:zenodo.org:39553</dc:identifier>
  <dc:rights>info:eu-repo/semantics/openAccess</dc:rights>
  <dc:rights>http://www.opendefinition.org/licenses/cc-by</dc:rights>
  <dc:source>JOURNAL OF COORDINATION CHEMISTRY 62(6) 1005-1014</dc:source>
  <dc:title>A Co(III) complex with a tridentate amine-imine-oxime ligand from 1,2,3,4-tetrahydroquinazoline: synthesis, crystal structure, spectroscopic and thermal characterization</dc:title>
  <dc:type>info:eu-repo/semantics/article</dc:type>
  <dc:type>publication-article</dc:type>
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