1 Ocak 2009 Dergi makalesi Açık Erişim

Colak, Alper Tolga; Irez, Gazi; Mutlu, Hasene; Hokelek, Tuncer; Caylak, Nagihan

JSON-LD (schema.org)

{
  "@context": "https://schema.org/", 
  "@id": 39553, 
  "@type": "ScholarlyArticle", 
  "creator": [
    {
      "@type": "Person", 
      "affiliation": "Dumlupmar Univ, Dept Chem, Fac Arts & Sci, Kutahya, Turkey", 
      "name": "Colak, Alper Tolga"
    }, 
    {
      "@type": "Person", 
      "affiliation": "Uludag Univ, Dept Chem, Fac Arts & Sci, Bursa, Turkey", 
      "name": "Irez, Gazi"
    }, 
    {
      "@type": "Person", 
      "affiliation": "Uludag Univ, Dept Chem, Fac Arts & Sci, Bursa, Turkey", 
      "name": "Mutlu, Hasene"
    }, 
    {
      "@type": "Person", 
      "affiliation": "Hacettepe Univ, Dept Phys, Fac Engn, TR-06800 Beytepe, Turkey", 
      "name": "Hokelek, Tuncer"
    }, 
    {
      "@type": "Person", 
      "affiliation": "Sakarya Univ, Dept Phys, Fac Arts & Sci, TR-54187 Adapazari, Turkey", 
      "name": "Caylak, Nagihan"
    }
  ], 
  "datePublished": "2009-01-01", 
  "description": "A cobalt(III) complex [Co(L)2]Cl PPO H2O (1) (HL = 1-(2-aminobenzylimino)-1-phenyl-propan-2-one oxime, PPO = 1-phenyl-1,2-propanedione-2-oxime) has been synthesized and characterized by elemental analyses, spectral, thermal, magnetic and molar conductance measurements and single crystal X-ray diffraction. It crystallizes in the monoclinic crystal system, space group P21/c. Complex 1 consists of one uncoordinated water, one 1-phenyl-1,2-propanedione-2-oxime molecule, one bis[1-(2-aminobenzylimino)-1-phenyl-propan-2-one oxime]cobalt(III) cation and one uncoordinated chloride. The coordination geometry around Co is slightly distorted octahedral, completed with six nitrogens of two L- ligands. The oxime moieties have E configurations. In the crystal structure, intramolecular O-HCl and N-HO and intermolecular N-HO, O-HCl and N-HCl hydrogen bonds link the molecules into chains parallel to the c axis; hydrogen-bonded PPO molecules fill the spaces between the chains and stabilization of the structure.", 
  "headline": "A Co(III) complex with a tridentate amine-imine-oxime ligand from 1,2,3,4-tetrahydroquinazoline: synthesis, crystal structure, spectroscopic and thermal characterization", 
  "identifier": 39553, 
  "image": "https://aperta.ulakbim.gov.tr/static/img/logo/aperta_logo_with_icon.svg", 
  "license": "http://www.opendefinition.org/licenses/cc-by", 
  "name": "A Co(III) complex with a tridentate amine-imine-oxime ligand from 1,2,3,4-tetrahydroquinazoline: synthesis, crystal structure, spectroscopic and thermal characterization", 
  "url": "https://aperta.ulakbim.gov.tr/record/39553"
}