1 Ocak 2009 Dergi makalesi Açık Erişim

Colak, Alper Tolga; Irez, Gazi; Mutlu, Hasene; Hokelek, Tuncer; Caylak, Nagihan

Citation Style Language JSON

{
  "DOI": "10.1080/00958970802345831", 
  "abstract": "A cobalt(III) complex [Co(L)2]Cl PPO H2O (1) (HL = 1-(2-aminobenzylimino)-1-phenyl-propan-2-one oxime, PPO = 1-phenyl-1,2-propanedione-2-oxime) has been synthesized and characterized by elemental analyses, spectral, thermal, magnetic and molar conductance measurements and single crystal X-ray diffraction. It crystallizes in the monoclinic crystal system, space group P21/c. Complex 1 consists of one uncoordinated water, one 1-phenyl-1,2-propanedione-2-oxime molecule, one bis[1-(2-aminobenzylimino)-1-phenyl-propan-2-one oxime]cobalt(III) cation and one uncoordinated chloride. The coordination geometry around Co is slightly distorted octahedral, completed with six nitrogens of two L- ligands. The oxime moieties have E configurations. In the crystal structure, intramolecular O-HCl and N-HO and intermolecular N-HO, O-HCl and N-HCl hydrogen bonds link the molecules into chains parallel to the c axis; hydrogen-bonded PPO molecules fill the spaces between the chains and stabilization of the structure.", 
  "author": [
    {
      "family": "Colak", 
      "given": " Alper Tolga"
    }, 
    {
      "family": "Irez", 
      "given": " Gazi"
    }, 
    {
      "family": "Mutlu", 
      "given": " Hasene"
    }, 
    {
      "family": "Hokelek", 
      "given": " Tuncer"
    }, 
    {
      "family": "Caylak", 
      "given": " Nagihan"
    }
  ], 
  "container_title": "JOURNAL OF COORDINATION CHEMISTRY", 
  "id": "39553", 
  "issue": "6", 
  "issued": {
    "date-parts": [
      [
        2009, 
        1, 
        1
      ]
    ]
  }, 
  "page": "1005-1014", 
  "title": "A Co(III) complex with a tridentate amine-imine-oxime ligand from 1,2,3,4-tetrahydroquinazoline: synthesis, crystal structure, spectroscopic and thermal characterization", 
  "type": "article-journal", 
  "volume": "62"
}