1 Ocak 2009 Dergi makalesi Açık Erişim

Colak, Alper Tolga; Irez, Gazi; Mutlu, Hasene; Hokelek, Tuncer; Caylak, Nagihan

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  <identifier identifierType="URL">https://aperta.ulakbim.gov.tr/record/39553</identifier>
  <creators>
    <creator>
      <creatorName>Colak, Alper Tolga</creatorName>
      <givenName>Alper Tolga</givenName>
      <familyName>Colak</familyName>
      <affiliation>Dumlupmar Univ, Dept Chem, Fac Arts &amp; Sci, Kutahya, Turkey</affiliation>
    </creator>
    <creator>
      <creatorName>Irez, Gazi</creatorName>
      <givenName>Gazi</givenName>
      <familyName>Irez</familyName>
      <affiliation>Uludag Univ, Dept Chem, Fac Arts &amp; Sci, Bursa, Turkey</affiliation>
    </creator>
    <creator>
      <creatorName>Mutlu, Hasene</creatorName>
      <givenName>Hasene</givenName>
      <familyName>Mutlu</familyName>
      <affiliation>Uludag Univ, Dept Chem, Fac Arts &amp; Sci, Bursa, Turkey</affiliation>
    </creator>
    <creator>
      <creatorName>Hokelek, Tuncer</creatorName>
      <givenName>Tuncer</givenName>
      <familyName>Hokelek</familyName>
      <affiliation>Hacettepe Univ, Dept Phys, Fac Engn, TR-06800 Beytepe, Turkey</affiliation>
    </creator>
    <creator>
      <creatorName>Caylak, Nagihan</creatorName>
      <givenName>Nagihan</givenName>
      <familyName>Caylak</familyName>
      <affiliation>Sakarya Univ, Dept Phys, Fac Arts &amp; Sci, TR-54187 Adapazari, Turkey</affiliation>
    </creator>
  </creators>
  <titles>
    <title>A Co(Iii) Complex With A Tridentate Amine-Imine-Oxime Ligand From 1,2,3,4-Tetrahydroquinazoline: Synthesis, Crystal Structure, Spectroscopic And Thermal Characterization</title>
  </titles>
  <publisher>Aperta</publisher>
  <publicationYear>2009</publicationYear>
  <dates>
    <date dateType="Issued">2009-01-01</date>
  </dates>
  <resourceType resourceTypeGeneral="Text">Journal article</resourceType>
  <alternateIdentifiers>
    <alternateIdentifier alternateIdentifierType="url">https://aperta.ulakbim.gov.tr/record/39553</alternateIdentifier>
  </alternateIdentifiers>
  <relatedIdentifiers>
    <relatedIdentifier relatedIdentifierType="DOI" relationType="IsIdenticalTo">10.1080/00958970802345831</relatedIdentifier>
  </relatedIdentifiers>
  <rightsList>
    <rights rightsURI="http://www.opendefinition.org/licenses/cc-by">Creative Commons Attribution</rights>
    <rights rightsURI="info:eu-repo/semantics/openAccess">Open Access</rights>
  </rightsList>
  <descriptions>
    <description descriptionType="Abstract">A cobalt(III) complex [Co(L)2]Cl PPO H2O (1) (HL = 1-(2-aminobenzylimino)-1-phenyl-propan-2-one oxime, PPO = 1-phenyl-1,2-propanedione-2-oxime) has been synthesized and characterized by elemental analyses, spectral, thermal, magnetic and molar conductance measurements and single crystal X-ray diffraction. It crystallizes in the monoclinic crystal system, space group P21/c. Complex 1 consists of one uncoordinated water, one 1-phenyl-1,2-propanedione-2-oxime molecule, one bis[1-(2-aminobenzylimino)-1-phenyl-propan-2-one oxime]cobalt(III) cation and one uncoordinated chloride. The coordination geometry around Co is slightly distorted octahedral, completed with six nitrogens of two L- ligands. The oxime moieties have E configurations. In the crystal structure, intramolecular O-HCl and N-HO and intermolecular N-HO, O-HCl and N-HCl hydrogen bonds link the molecules into chains parallel to the c axis; hydrogen-bonded PPO molecules fill the spaces between the chains and stabilization of the structure.</description>
  </descriptions>
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