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Application of nanofiltration for Rare Earth Elements recovery from coal fly ash leachate: Performance and cost evaluation

Mutlu, Borte Kose; Cantoni, Beatrice; Turolla, Andrea; Antonelli, Manuela; Hsu-Kim, Heileen; Wiesner, Mark R.


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        "affiliation": "Duke Univ, Dept Civil & Environm Engn, Pratt Sch Engn, Durham, NC 27708 USA", 
        "name": "Mutlu, Borte Kose"
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      {
        "affiliation": "Politecn Milan, Dept Civil & Environm Engn DICA, Environm Sect, Piazza Leonardo da Vinci 32, I-20133 Milan, Italy", 
        "name": "Cantoni, Beatrice"
      }, 
      {
        "affiliation": "Politecn Milan, Dept Civil & Environm Engn DICA, Environm Sect, Piazza Leonardo da Vinci 32, I-20133 Milan, Italy", 
        "name": "Turolla, Andrea"
      }, 
      {
        "affiliation": "Politecn Milan, Dept Civil & Environm Engn DICA, Environm Sect, Piazza Leonardo da Vinci 32, I-20133 Milan, Italy", 
        "name": "Antonelli, Manuela"
      }, 
      {
        "affiliation": "Duke Univ, Dept Civil & Environm Engn, Pratt Sch Engn, Durham, NC 27708 USA", 
        "name": "Hsu-Kim, Heileen"
      }, 
      {
        "affiliation": "Duke Univ, Dept Civil & Environm Engn, Pratt Sch Engn, Durham, NC 27708 USA", 
        "name": "Wiesner, Mark R."
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    ], 
    "description": "This work evaluated nanofiltration (NF) as a potential step in the recovery process of Rare Earth Elements (REEs) from leachates of coal combustion fly ashes. A pre-treatment step, by pH adjustment and microfiltration (MF), has been studied to separate REEs by major elements. The individual and combined effects of applied pressure (12-24 bar) and NF feed acidity (pH 1.5-3.5) on rejection of six critical REEs and permeate flux have been investigated via response surface methodology (RSM). The resulting model equations were used to develop a cost model for the recovery chain, in order to select the optimum NF operating conditions. The optimization of the REE recovery chain, including pre-treatment and NF, was done with respect to the objective of maximizing the difference between NF concentrate economic value and treatment cost. NF with an appropriate MF pre-treatment has been effective in concentrating REEs from fly ash leachate, reaching the maximum potential gain at the optimum operating conditions of 12 bar and pH 3.5.", 
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      "pages": "309-317", 
      "title": "CHEMICAL ENGINEERING JOURNAL", 
      "volume": "349"
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    "publication_date": "2018-01-01", 
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    "title": "Application of nanofiltration for Rare Earth Elements recovery from coal fly ash leachate: Performance and cost evaluation"
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