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Application of nanofiltration for Rare Earth Elements recovery from coal fly ash leachate: Performance and cost evaluation

Mutlu, Borte Kose; Cantoni, Beatrice; Turolla, Andrea; Antonelli, Manuela; Hsu-Kim, Heileen; Wiesner, Mark R.


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{
  "DOI": "10.1016/j.cej.2018.05.080", 
  "abstract": "This work evaluated nanofiltration (NF) as a potential step in the recovery process of Rare Earth Elements (REEs) from leachates of coal combustion fly ashes. A pre-treatment step, by pH adjustment and microfiltration (MF), has been studied to separate REEs by major elements. The individual and combined effects of applied pressure (12-24 bar) and NF feed acidity (pH 1.5-3.5) on rejection of six critical REEs and permeate flux have been investigated via response surface methodology (RSM). The resulting model equations were used to develop a cost model for the recovery chain, in order to select the optimum NF operating conditions. The optimization of the REE recovery chain, including pre-treatment and NF, was done with respect to the objective of maximizing the difference between NF concentrate economic value and treatment cost. NF with an appropriate MF pre-treatment has been effective in concentrating REEs from fly ash leachate, reaching the maximum potential gain at the optimum operating conditions of 12 bar and pH 3.5.", 
  "author": [
    {
      "family": "Mutlu", 
      "given": " Borte Kose"
    }, 
    {
      "family": "Cantoni", 
      "given": " Beatrice"
    }, 
    {
      "family": "Turolla", 
      "given": " Andrea"
    }, 
    {
      "family": "Antonelli", 
      "given": " Manuela"
    }, 
    {
      "family": "Hsu-Kim", 
      "given": " Heileen"
    }, 
    {
      "family": "Wiesner", 
      "given": " Mark R."
    }
  ], 
  "container_title": "CHEMICAL ENGINEERING JOURNAL", 
  "id": "36935", 
  "issued": {
    "date-parts": [
      [
        2018, 
        1, 
        1
      ]
    ]
  }, 
  "page": "309-317", 
  "title": "Application of nanofiltration for Rare Earth Elements recovery from coal fly ash leachate: Performance and cost evaluation", 
  "type": "article-journal", 
  "volume": "349"
}
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