Dergi makalesi Açık Erişim
Filiz, Bilge Coskuner; Figen, Aysel Kanturk; Piskin, Sabriye
<?xml version='1.0' encoding='utf-8'?> <oai_dc:dc xmlns:dc="http://purl.org/dc/elements/1.1/" xmlns:oai_dc="http://www.openarchives.org/OAI/2.0/oai_dc/" xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance" xsi:schemaLocation="http://www.openarchives.org/OAI/2.0/oai_dc/ http://www.openarchives.org/OAI/2.0/oai_dc.xsd"> <dc:creator>Filiz, Bilge Coskuner</dc:creator> <dc:creator>Figen, Aysel Kanturk</dc:creator> <dc:creator>Piskin, Sabriye</dc:creator> <dc:date>2018-01-01</dc:date> <dc:description>A new hybrid of nanoparticles designed to enable efficient catalysis for hydrogen generation (NPs) include a dual combination of Co, Ni, and Cu transition metals. These nanoparticles are made by altering metals and molar ratios (x: 0.25, 0.50, and 0.75) and synthesized for hydrogen generation by hydrolytic dehydrogenation of ammonia borane (NH3BH3). A synergistic effect of dual combination on the induction period and dehydrogenation rate (DR) is found. Kinetic interpretation and thermodynamic studies demonstrate that the Co0.50Cu0.50/NPs catalyst shows superior activation (DR = 10.561 H-2 min(-1).g(-1)cat and E-a = 38.12 kJ mol(-1)) with a synergistic effect and meet the criteria of The United States Department of Energy (DOE) targets for onboard hydrogen production systems for light-duty vehicles.</dc:description> <dc:identifier>https://aperta.ulakbim.gov.trrecord/36003</dc:identifier> <dc:identifier>oai:zenodo.org:36003</dc:identifier> <dc:rights>info:eu-repo/semantics/openAccess</dc:rights> <dc:rights>http://www.opendefinition.org/licenses/cc-by</dc:rights> <dc:source>APPLIED CATALYSIS A-GENERAL 550 320-330</dc:source> <dc:title>Dual combining transition metal hybrid nanoparticles for ammonia borane hydrolytic dehydrogenation</dc:title> <dc:type>info:eu-repo/semantics/article</dc:type> <dc:type>publication-article</dc:type> </oai_dc:dc>
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