1 Ocak 2018 Dergi makalesi Açık Erişim

Filiz, Bilge Coskuner; Figen, Aysel Kanturk; Piskin, Sabriye

Citation Style Language JSON

{
  "DOI": "10.1016/j.apcata.2017.11.022", 
  "abstract": "A new hybrid of nanoparticles designed to enable efficient catalysis for hydrogen generation (NPs) include a dual combination of Co, Ni, and Cu transition metals. These nanoparticles are made by altering metals and molar ratios (x: 0.25, 0.50, and 0.75) and synthesized for hydrogen generation by hydrolytic dehydrogenation of ammonia borane (NH3BH3). A synergistic effect of dual combination on the induction period and dehydrogenation rate (DR) is found. Kinetic interpretation and thermodynamic studies demonstrate that the Co0.50Cu0.50/NPs catalyst shows superior activation (DR = 10.561 H-2 min(-1).g(-1)cat and E-a = 38.12 kJ mol(-1)) with a synergistic effect and meet the criteria of The United States Department of Energy (DOE) targets for onboard hydrogen production systems for light-duty vehicles.", 
  "author": [
    {
      "family": "Filiz", 
      "given": " Bilge Coskuner"
    }, 
    {
      "family": "Figen", 
      "given": " Aysel Kanturk"
    }, 
    {
      "family": "Piskin", 
      "given": " Sabriye"
    }
  ], 
  "container_title": "APPLIED CATALYSIS A-GENERAL", 
  "id": "36003", 
  "issued": {
    "date-parts": [
      [
        2018, 
        1, 
        1
      ]
    ]
  }, 
  "page": "320-330", 
  "title": "Dual combining transition metal hybrid nanoparticles for ammonia borane hydrolytic dehydrogenation", 
  "type": "article-journal", 
  "volume": "550"
}