Dergi makalesi Açık Erişim
Filiz, Bilge Coskuner; Figen, Aysel Kanturk; Piskin, Sabriye
{ "@context": "https://schema.org/", "@id": 36003, "@type": "ScholarlyArticle", "creator": [ { "@type": "Person", "affiliation": "Yildiz Tech Univ, Dept Chem Engn, TR-34210 Istanbul, Turkey", "name": "Filiz, Bilge Coskuner" }, { "@type": "Person", "affiliation": "Yildiz Tech Univ, Dept Chem Engn, TR-34210 Istanbul, Turkey", "name": "Figen, Aysel Kanturk" }, { "@type": "Person", "affiliation": "Yildiz Tech Univ, Dept Chem Engn, TR-34210 Istanbul, Turkey", "name": "Piskin, Sabriye" } ], "datePublished": "2018-01-01", "description": "A new hybrid of nanoparticles designed to enable efficient catalysis for hydrogen generation (NPs) include a dual combination of Co, Ni, and Cu transition metals. These nanoparticles are made by altering metals and molar ratios (x: 0.25, 0.50, and 0.75) and synthesized for hydrogen generation by hydrolytic dehydrogenation of ammonia borane (NH3BH3). A synergistic effect of dual combination on the induction period and dehydrogenation rate (DR) is found. Kinetic interpretation and thermodynamic studies demonstrate that the Co0.50Cu0.50/NPs catalyst shows superior activation (DR = 10.561 H-2 min(-1).g(-1)cat and E-a = 38.12 kJ mol(-1)) with a synergistic effect and meet the criteria of The United States Department of Energy (DOE) targets for onboard hydrogen production systems for light-duty vehicles.", "headline": "Dual combining transition metal hybrid nanoparticles for ammonia borane hydrolytic dehydrogenation", "identifier": 36003, "image": "https://aperta.ulakbim.gov.tr/static/img/logo/aperta_logo_with_icon.svg", "license": "http://www.opendefinition.org/licenses/cc-by", "name": "Dual combining transition metal hybrid nanoparticles for ammonia borane hydrolytic dehydrogenation", "url": "https://aperta.ulakbim.gov.tr/record/36003" }
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