1 Ocak 2018 Dergi makalesi Açık Erişim

Filiz, Bilge Coskuner; Figen, Aysel Kanturk; Piskin, Sabriye

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  <identifier identifierType="URL">https://aperta.ulakbim.gov.tr/record/36003</identifier>
  <creators>
    <creator>
      <creatorName>Filiz, Bilge Coskuner</creatorName>
      <givenName>Bilge Coskuner</givenName>
      <familyName>Filiz</familyName>
      <affiliation>Yildiz Tech Univ, Dept Chem Engn, TR-34210 Istanbul, Turkey</affiliation>
    </creator>
    <creator>
      <creatorName>Figen, Aysel Kanturk</creatorName>
      <givenName>Aysel Kanturk</givenName>
      <familyName>Figen</familyName>
      <affiliation>Yildiz Tech Univ, Dept Chem Engn, TR-34210 Istanbul, Turkey</affiliation>
    </creator>
    <creator>
      <creatorName>Piskin, Sabriye</creatorName>
      <givenName>Sabriye</givenName>
      <familyName>Piskin</familyName>
      <affiliation>Yildiz Tech Univ, Dept Chem Engn, TR-34210 Istanbul, Turkey</affiliation>
    </creator>
  </creators>
  <titles>
    <title>Dual Combining Transition Metal Hybrid Nanoparticles For Ammonia Borane Hydrolytic Dehydrogenation</title>
  </titles>
  <publisher>Aperta</publisher>
  <publicationYear>2018</publicationYear>
  <dates>
    <date dateType="Issued">2018-01-01</date>
  </dates>
  <resourceType resourceTypeGeneral="Text">Journal article</resourceType>
  <alternateIdentifiers>
    <alternateIdentifier alternateIdentifierType="url">https://aperta.ulakbim.gov.tr/record/36003</alternateIdentifier>
  </alternateIdentifiers>
  <relatedIdentifiers>
    <relatedIdentifier relatedIdentifierType="DOI" relationType="IsIdenticalTo">10.1016/j.apcata.2017.11.022</relatedIdentifier>
  </relatedIdentifiers>
  <rightsList>
    <rights rightsURI="http://www.opendefinition.org/licenses/cc-by">Creative Commons Attribution</rights>
    <rights rightsURI="info:eu-repo/semantics/openAccess">Open Access</rights>
  </rightsList>
  <descriptions>
    <description descriptionType="Abstract">A new hybrid of nanoparticles designed to enable efficient catalysis for hydrogen generation (NPs) include a dual combination of Co, Ni, and Cu transition metals. These nanoparticles are made by altering metals and molar ratios (x: 0.25, 0.50, and 0.75) and synthesized for hydrogen generation by hydrolytic dehydrogenation of ammonia borane (NH3BH3). A synergistic effect of dual combination on the induction period and dehydrogenation rate (DR) is found. Kinetic interpretation and thermodynamic studies demonstrate that the Co0.50Cu0.50/NPs catalyst shows superior activation (DR = 10.561 H-2 min(-1).g(-1)cat and E-a = 38.12 kJ mol(-1)) with a synergistic effect and meet the criteria of The United States Department of Energy (DOE) targets for onboard hydrogen production systems for light-duty vehicles.</description>
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