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A New pi-conjugated 1,7-diphenoxy-perylene bisimide: Synthesis, characterization, photophysical and electrochemical properties

Pakseresht, Mayram; Bodapati, Jagadeesh B.; Icil, Huriye


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<oai_dc:dc xmlns:dc="http://purl.org/dc/elements/1.1/" xmlns:oai_dc="http://www.openarchives.org/OAI/2.0/oai_dc/" xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance" xsi:schemaLocation="http://www.openarchives.org/OAI/2.0/oai_dc/ http://www.openarchives.org/OAI/2.0/oai_dc.xsd">
  <dc:creator>Pakseresht, Mayram</dc:creator>
  <dc:creator>Bodapati, Jagadeesh B.</dc:creator>
  <dc:creator>Icil, Huriye</dc:creator>
  <dc:date>2018-01-01</dc:date>
  <dc:description>A novel pi-conjugated 1,7-diphenoxy-perylene bisimide (perylene diimides, PDIs) (4) was synthesized starting from 1,7(6)-diphenoxyperylene-3,4,9,10-tetracarboxylic bisanhydride (3). N,N'-bis(4-hydroxyphenyl)-perylene-3,4,9,10-tetracarboxy bisimide (1) was synthesized and characterized also for the comparison between a non-bay substituted symmetrical perylene diimide and the bay substituted symmetrical perylene diimide with the same substituents at the PDI imide positions. Positive and weak solvatochromic effect for the compounds 3 and 4 was apparently observed in polar media. The absolute positions of LUMO and HOMO values of 1 and 3 in solution were -3.775 eV/- 6.035 eV and -3.971 eV/- 6.041, respectively. The HOMO, LUMO and E-g values for the compound 4 were not calculated due to the non-resolved reduction peaks most probably due to aggregation.</dc:description>
  <dc:identifier>https://aperta.ulakbim.gov.trrecord/30709</dc:identifier>
  <dc:identifier>oai:zenodo.org:30709</dc:identifier>
  <dc:rights>info:eu-repo/semantics/openAccess</dc:rights>
  <dc:rights>http://www.opendefinition.org/licenses/cc-by</dc:rights>
  <dc:source>JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY 360 270-277</dc:source>
  <dc:title>A New pi-conjugated 1,7-diphenoxy-perylene bisimide: Synthesis, characterization, photophysical and electrochemical properties</dc:title>
  <dc:type>info:eu-repo/semantics/article</dc:type>
  <dc:type>publication-article</dc:type>
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