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A New pi-conjugated 1,7-diphenoxy-perylene bisimide: Synthesis, characterization, photophysical and electrochemical properties

Pakseresht, Mayram; Bodapati, Jagadeesh B.; Icil, Huriye


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{
  "DOI": "10.1016/j.jphotochem.2018.04.043", 
  "abstract": "A novel pi-conjugated 1,7-diphenoxy-perylene bisimide (perylene diimides, PDIs) (4) was synthesized starting from 1,7(6)-diphenoxyperylene-3,4,9,10-tetracarboxylic bisanhydride (3). N,N'-bis(4-hydroxyphenyl)-perylene-3,4,9,10-tetracarboxy bisimide (1) was synthesized and characterized also for the comparison between a non-bay substituted symmetrical perylene diimide and the bay substituted symmetrical perylene diimide with the same substituents at the PDI imide positions. Positive and weak solvatochromic effect for the compounds 3 and 4 was apparently observed in polar media. The absolute positions of LUMO and HOMO values of 1 and 3 in solution were -3.775 eV/- 6.035 eV and -3.971 eV/- 6.041, respectively. The HOMO, LUMO and E-g values for the compound 4 were not calculated due to the non-resolved reduction peaks most probably due to aggregation.", 
  "author": [
    {
      "family": "Pakseresht", 
      "given": " Mayram"
    }, 
    {
      "family": "Bodapati", 
      "given": " Jagadeesh B."
    }, 
    {
      "family": "Icil", 
      "given": " Huriye"
    }
  ], 
  "container_title": "JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY", 
  "id": "30709", 
  "issued": {
    "date-parts": [
      [
        2018, 
        1, 
        1
      ]
    ]
  }, 
  "page": "270-277", 
  "title": "A New pi-conjugated 1,7-diphenoxy-perylene bisimide: Synthesis, characterization, photophysical and electrochemical properties", 
  "type": "article-journal", 
  "volume": "360"
}
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