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Pakseresht, Mayram; Bodapati, Jagadeesh B.; Icil, Huriye
{ "DOI": "10.1016/j.jphotochem.2018.04.043", "abstract": "A novel pi-conjugated 1,7-diphenoxy-perylene bisimide (perylene diimides, PDIs) (4) was synthesized starting from 1,7(6)-diphenoxyperylene-3,4,9,10-tetracarboxylic bisanhydride (3). N,N'-bis(4-hydroxyphenyl)-perylene-3,4,9,10-tetracarboxy bisimide (1) was synthesized and characterized also for the comparison between a non-bay substituted symmetrical perylene diimide and the bay substituted symmetrical perylene diimide with the same substituents at the PDI imide positions. Positive and weak solvatochromic effect for the compounds 3 and 4 was apparently observed in polar media. The absolute positions of LUMO and HOMO values of 1 and 3 in solution were -3.775 eV/- 6.035 eV and -3.971 eV/- 6.041, respectively. The HOMO, LUMO and E-g values for the compound 4 were not calculated due to the non-resolved reduction peaks most probably due to aggregation.", "author": [ { "family": "Pakseresht", "given": " Mayram" }, { "family": "Bodapati", "given": " Jagadeesh B." }, { "family": "Icil", "given": " Huriye" } ], "container_title": "JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY", "id": "30709", "issued": { "date-parts": [ [ 2018, 1, 1 ] ] }, "page": "270-277", "title": "A New pi-conjugated 1,7-diphenoxy-perylene bisimide: Synthesis, characterization, photophysical and electrochemical properties", "type": "article-journal", "volume": "360" }
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