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A New pi-conjugated 1,7-diphenoxy-perylene bisimide: Synthesis, characterization, photophysical and electrochemical properties

Pakseresht, Mayram; Bodapati, Jagadeesh B.; Icil, Huriye


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{
  "@context": "https://schema.org/", 
  "@id": 30709, 
  "@type": "ScholarlyArticle", 
  "creator": [
    {
      "@type": "Person", 
      "affiliation": "Eastern Mediterranean Univ, Fac Arts & Sci, Dept Chem, Mersin 10, Famagusta, N Cyprus, Turkey", 
      "name": "Pakseresht, Mayram"
    }, 
    {
      "@type": "Person", 
      "name": "Bodapati, Jagadeesh B."
    }, 
    {
      "@type": "Person", 
      "affiliation": "Eastern Mediterranean Univ, Fac Arts & Sci, Dept Chem, Mersin 10, Famagusta, N Cyprus, Turkey", 
      "name": "Icil, Huriye"
    }
  ], 
  "datePublished": "2018-01-01", 
  "description": "A novel pi-conjugated 1,7-diphenoxy-perylene bisimide (perylene diimides, PDIs) (4) was synthesized starting from 1,7(6)-diphenoxyperylene-3,4,9,10-tetracarboxylic bisanhydride (3). N,N'-bis(4-hydroxyphenyl)-perylene-3,4,9,10-tetracarboxy bisimide (1) was synthesized and characterized also for the comparison between a non-bay substituted symmetrical perylene diimide and the bay substituted symmetrical perylene diimide with the same substituents at the PDI imide positions. Positive and weak solvatochromic effect for the compounds 3 and 4 was apparently observed in polar media. The absolute positions of LUMO and HOMO values of 1 and 3 in solution were -3.775 eV/- 6.035 eV and -3.971 eV/- 6.041, respectively. The HOMO, LUMO and E-g values for the compound 4 were not calculated due to the non-resolved reduction peaks most probably due to aggregation.", 
  "headline": "A New pi-conjugated 1,7-diphenoxy-perylene bisimide: Synthesis, characterization, photophysical and electrochemical properties", 
  "identifier": 30709, 
  "image": "https://aperta.ulakbim.gov.tr/static/img/logo/aperta_logo_with_icon.svg", 
  "license": "http://www.opendefinition.org/licenses/cc-by", 
  "name": "A New pi-conjugated 1,7-diphenoxy-perylene bisimide: Synthesis, characterization, photophysical and electrochemical properties", 
  "url": "https://aperta.ulakbim.gov.tr/record/30709"
}
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