1 Ocak 2018 Dergi makalesi Açık Erişim

Pakseresht, Mayram; Bodapati, Jagadeesh B.; Icil, Huriye

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  <identifier identifierType="URL">https://aperta.ulakbim.gov.tr/record/30709</identifier>
  <creators>
    <creator>
      <creatorName>Pakseresht, Mayram</creatorName>
      <givenName>Mayram</givenName>
      <familyName>Pakseresht</familyName>
      <affiliation>Eastern Mediterranean Univ, Fac Arts &amp; Sci, Dept Chem, Mersin 10, Famagusta, N Cyprus, Turkey</affiliation>
    </creator>
    <creator>
      <creatorName>Bodapati, Jagadeesh B.</creatorName>
      <givenName>Jagadeesh B.</givenName>
      <familyName>Bodapati</familyName>
    </creator>
    <creator>
      <creatorName>Icil, Huriye</creatorName>
      <givenName>Huriye</givenName>
      <familyName>Icil</familyName>
      <affiliation>Eastern Mediterranean Univ, Fac Arts &amp; Sci, Dept Chem, Mersin 10, Famagusta, N Cyprus, Turkey</affiliation>
    </creator>
  </creators>
  <titles>
    <title>A New Pi-Conjugated 1,7-Diphenoxy-Perylene Bisimide: Synthesis, Characterization, Photophysical And Electrochemical Properties</title>
  </titles>
  <publisher>Aperta</publisher>
  <publicationYear>2018</publicationYear>
  <dates>
    <date dateType="Issued">2018-01-01</date>
  </dates>
  <resourceType resourceTypeGeneral="Text">Journal article</resourceType>
  <alternateIdentifiers>
    <alternateIdentifier alternateIdentifierType="url">https://aperta.ulakbim.gov.tr/record/30709</alternateIdentifier>
  </alternateIdentifiers>
  <relatedIdentifiers>
    <relatedIdentifier relatedIdentifierType="DOI" relationType="IsIdenticalTo">10.1016/j.jphotochem.2018.04.043</relatedIdentifier>
  </relatedIdentifiers>
  <rightsList>
    <rights rightsURI="http://www.opendefinition.org/licenses/cc-by">Creative Commons Attribution</rights>
    <rights rightsURI="info:eu-repo/semantics/openAccess">Open Access</rights>
  </rightsList>
  <descriptions>
    <description descriptionType="Abstract">A novel pi-conjugated 1,7-diphenoxy-perylene bisimide (perylene diimides, PDIs) (4) was synthesized starting from 1,7(6)-diphenoxyperylene-3,4,9,10-tetracarboxylic bisanhydride (3). N,N'-bis(4-hydroxyphenyl)-perylene-3,4,9,10-tetracarboxy bisimide (1) was synthesized and characterized also for the comparison between a non-bay substituted symmetrical perylene diimide and the bay substituted symmetrical perylene diimide with the same substituents at the PDI imide positions. Positive and weak solvatochromic effect for the compounds 3 and 4 was apparently observed in polar media. The absolute positions of LUMO and HOMO values of 1 and 3 in solution were -3.775 eV/- 6.035 eV and -3.971 eV/- 6.041, respectively. The HOMO, LUMO and E-g values for the compound 4 were not calculated due to the non-resolved reduction peaks most probably due to aggregation.</description>
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