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Effect of Ti sublayer on the ORR catalytic efficiency of dc magnetron sputtered thin Pt films

Ozturk, Osman; Ozdemir, Oguz Kaan; Ulusoy, Isilay; Ahsen, Ali Sems; Slavcheva, Evelina


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  <dc:creator>Ozturk, Osman</dc:creator>
  <dc:creator>Ozdemir, Oguz Kaan</dc:creator>
  <dc:creator>Ulusoy, Isilay</dc:creator>
  <dc:creator>Ahsen, Ali Sems</dc:creator>
  <dc:creator>Slavcheva, Evelina</dc:creator>
  <dc:date>2010-01-01</dc:date>
  <dc:description>A series of thin Pt films were deposited by dc magnetron sputtering directly on a commercial hydrophobic carbon paper substrate having a thin microporous Vulcan-XC72 layer or upon a thin Ti sublayer sputtered on the top of the microporous carbon film. The electrocatalytic properties of the sputtered Pt films toward the oxygen reduction reaction were investigated in 0.5 M H2SO4 solution and in a hydrogen PEM fuel cell. The catalyst with ultralow Pt loading of 22 mu g cm(-2) deposited on a 33 angstrom thick Ti sublayer is robust, mechanically stable, possesses highly developed surface area and improved catalytic efficiency. Its performance as a MEA cathode in a single hydrogen PEM fuel cell (577 mA cm(-2) at 0.4 V cell voltages and a maximum power of 0.954W) proved to be much superior compared to that of MEA with the same cathode Pt loading but without Ti sublayer (173 mA cm(-2) at 0.4 V, 0.231W, respectively). (C) 2010 Professor T. Nejat Veziroglu. Published by Elsevier Ltd. All rights reserved.</dc:description>
  <dc:identifier>https://aperta.ulakbim.gov.trrecord/27811</dc:identifier>
  <dc:identifier>oai:zenodo.org:27811</dc:identifier>
  <dc:rights>info:eu-repo/semantics/openAccess</dc:rights>
  <dc:rights>http://www.opendefinition.org/licenses/cc-by</dc:rights>
  <dc:source>INTERNATIONAL JOURNAL OF HYDROGEN ENERGY 35(10) 4466-4473</dc:source>
  <dc:title>Effect of Ti sublayer on the ORR catalytic efficiency of dc magnetron sputtered thin Pt films</dc:title>
  <dc:type>info:eu-repo/semantics/article</dc:type>
  <dc:type>publication-article</dc:type>
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