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Effect of Ti sublayer on the ORR catalytic efficiency of dc magnetron sputtered thin Pt films

Ozturk, Osman; Ozdemir, Oguz Kaan; Ulusoy, Isilay; Ahsen, Ali Sems; Slavcheva, Evelina


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{
  "@context": "https://schema.org/", 
  "@id": 27811, 
  "@type": "ScholarlyArticle", 
  "creator": [
    {
      "@type": "Person", 
      "affiliation": "Gebze Inst Technol, Dept Phys, Nanotechnol Res Ctr, TR-41400 Cayirova Gebze, Kocaeli, Turkey", 
      "name": "Ozturk, Osman"
    }, 
    {
      "@type": "Person", 
      "name": "Ozdemir, Oguz Kaan"
    }, 
    {
      "@type": "Person", 
      "name": "Ulusoy, Isilay"
    }, 
    {
      "@type": "Person", 
      "name": "Ahsen, Ali Sems"
    }, 
    {
      "@type": "Person", 
      "affiliation": "Bulgarian Acad Sci, Inst Electrochem & Energy Syst, Sofia, Bulgaria", 
      "name": "Slavcheva, Evelina"
    }
  ], 
  "datePublished": "2010-01-01", 
  "description": "A series of thin Pt films were deposited by dc magnetron sputtering directly on a commercial hydrophobic carbon paper substrate having a thin microporous Vulcan-XC72 layer or upon a thin Ti sublayer sputtered on the top of the microporous carbon film. The electrocatalytic properties of the sputtered Pt films toward the oxygen reduction reaction were investigated in 0.5 M H2SO4 solution and in a hydrogen PEM fuel cell. The catalyst with ultralow Pt loading of 22 mu g cm(-2) deposited on a 33 angstrom thick Ti sublayer is robust, mechanically stable, possesses highly developed surface area and improved catalytic efficiency. Its performance as a MEA cathode in a single hydrogen PEM fuel cell (577 mA cm(-2) at 0.4 V cell voltages and a maximum power of 0.954W) proved to be much superior compared to that of MEA with the same cathode Pt loading but without Ti sublayer (173 mA cm(-2) at 0.4 V, 0.231W, respectively). (C) 2010 Professor T. Nejat Veziroglu. Published by Elsevier Ltd. All rights reserved.", 
  "headline": "Effect of Ti sublayer on the ORR catalytic efficiency of dc magnetron sputtered thin Pt films", 
  "identifier": 27811, 
  "image": "https://aperta.ulakbim.gov.tr/static/img/logo/aperta_logo_with_icon.svg", 
  "license": "http://www.opendefinition.org/licenses/cc-by", 
  "name": "Effect of Ti sublayer on the ORR catalytic efficiency of dc magnetron sputtered thin Pt films", 
  "url": "https://aperta.ulakbim.gov.tr/record/27811"
}
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