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Effect of Ti sublayer on the ORR catalytic efficiency of dc magnetron sputtered thin Pt films

Ozturk, Osman; Ozdemir, Oguz Kaan; Ulusoy, Isilay; Ahsen, Ali Sems; Slavcheva, Evelina


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        "affiliation": "Gebze Inst Technol, Dept Phys, Nanotechnol Res Ctr, TR-41400 Cayirova Gebze, Kocaeli, Turkey", 
        "name": "Ozturk, Osman"
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      {
        "name": "Ozdemir, Oguz Kaan"
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      {
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      {
        "name": "Ahsen, Ali Sems"
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        "affiliation": "Bulgarian Acad Sci, Inst Electrochem & Energy Syst, Sofia, Bulgaria", 
        "name": "Slavcheva, Evelina"
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    "description": "A series of thin Pt films were deposited by dc magnetron sputtering directly on a commercial hydrophobic carbon paper substrate having a thin microporous Vulcan-XC72 layer or upon a thin Ti sublayer sputtered on the top of the microporous carbon film. The electrocatalytic properties of the sputtered Pt films toward the oxygen reduction reaction were investigated in 0.5 M H2SO4 solution and in a hydrogen PEM fuel cell. The catalyst with ultralow Pt loading of 22 mu g cm(-2) deposited on a 33 angstrom thick Ti sublayer is robust, mechanically stable, possesses highly developed surface area and improved catalytic efficiency. Its performance as a MEA cathode in a single hydrogen PEM fuel cell (577 mA cm(-2) at 0.4 V cell voltages and a maximum power of 0.954W) proved to be much superior compared to that of MEA with the same cathode Pt loading but without Ti sublayer (173 mA cm(-2) at 0.4 V, 0.231W, respectively). (C) 2010 Professor T. Nejat Veziroglu. Published by Elsevier Ltd. All rights reserved.", 
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      "issue": "10", 
      "pages": "4466-4473", 
      "title": "INTERNATIONAL JOURNAL OF HYDROGEN ENERGY", 
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