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Effect of Ti sublayer on the ORR catalytic efficiency of dc magnetron sputtered thin Pt films

Ozturk, Osman; Ozdemir, Oguz Kaan; Ulusoy, Isilay; Ahsen, Ali Sems; Slavcheva, Evelina


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  <identifier identifierType="URL">https://aperta.ulakbim.gov.tr/record/27811</identifier>
  <creators>
    <creator>
      <creatorName>Ozturk, Osman</creatorName>
      <givenName>Osman</givenName>
      <familyName>Ozturk</familyName>
      <affiliation>Gebze Inst Technol, Dept Phys, Nanotechnol Res Ctr, TR-41400 Cayirova Gebze, Kocaeli, Turkey</affiliation>
    </creator>
    <creator>
      <creatorName>Ozdemir, Oguz Kaan</creatorName>
      <givenName>Oguz Kaan</givenName>
      <familyName>Ozdemir</familyName>
    </creator>
    <creator>
      <creatorName>Ulusoy, Isilay</creatorName>
      <givenName>Isilay</givenName>
      <familyName>Ulusoy</familyName>
    </creator>
    <creator>
      <creatorName>Ahsen, Ali Sems</creatorName>
      <givenName>Ali Sems</givenName>
      <familyName>Ahsen</familyName>
    </creator>
    <creator>
      <creatorName>Slavcheva, Evelina</creatorName>
      <givenName>Evelina</givenName>
      <familyName>Slavcheva</familyName>
      <affiliation>Bulgarian Acad Sci, Inst Electrochem &amp; Energy Syst, Sofia, Bulgaria</affiliation>
    </creator>
  </creators>
  <titles>
    <title>Effect Of Ti Sublayer On The Orr Catalytic Efficiency Of Dc Magnetron Sputtered Thin Pt Films</title>
  </titles>
  <publisher>Aperta</publisher>
  <publicationYear>2010</publicationYear>
  <dates>
    <date dateType="Issued">2010-01-01</date>
  </dates>
  <resourceType resourceTypeGeneral="Text">Journal article</resourceType>
  <alternateIdentifiers>
    <alternateIdentifier alternateIdentifierType="url">https://aperta.ulakbim.gov.tr/record/27811</alternateIdentifier>
  </alternateIdentifiers>
  <relatedIdentifiers>
    <relatedIdentifier relatedIdentifierType="DOI" relationType="IsIdenticalTo">10.1016/j.ijhydene.2010.02.077</relatedIdentifier>
  </relatedIdentifiers>
  <rightsList>
    <rights rightsURI="http://www.opendefinition.org/licenses/cc-by">Creative Commons Attribution</rights>
    <rights rightsURI="info:eu-repo/semantics/openAccess">Open Access</rights>
  </rightsList>
  <descriptions>
    <description descriptionType="Abstract">A series of thin Pt films were deposited by dc magnetron sputtering directly on a commercial hydrophobic carbon paper substrate having a thin microporous Vulcan-XC72 layer or upon a thin Ti sublayer sputtered on the top of the microporous carbon film. The electrocatalytic properties of the sputtered Pt films toward the oxygen reduction reaction were investigated in 0.5 M H2SO4 solution and in a hydrogen PEM fuel cell. The catalyst with ultralow Pt loading of 22 mu g cm(-2) deposited on a 33 angstrom thick Ti sublayer is robust, mechanically stable, possesses highly developed surface area and improved catalytic efficiency. Its performance as a MEA cathode in a single hydrogen PEM fuel cell (577 mA cm(-2) at 0.4 V cell voltages and a maximum power of 0.954W) proved to be much superior compared to that of MEA with the same cathode Pt loading but without Ti sublayer (173 mA cm(-2) at 0.4 V, 0.231W, respectively). (C) 2010 Professor T. Nejat Veziroglu. Published by Elsevier Ltd. All rights reserved.</description>
  </descriptions>
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