1 Ocak 2010 Dergi makalesi Açık Erişim

Hur, Deniz; Ekti, Sultan Funda; Dal, Hakan

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  <dc:creator>Hur, Deniz</dc:creator>
  <dc:creator>Ekti, Sultan Funda</dc:creator>
  <dc:creator>Dal, Hakan</dc:creator>
  <dc:date>2010-01-01</dc:date>
  <dc:description>A new synthesis methodology has been presented for the preparation of the ferrocenoyl esters. Ferrocene carboxylic acid was derivatized using direct 1H-benzotriazole/SOCl2 methodology to prepare N-ferrocenoyl benzotriazole as a convenient tool for the functionalization of ferrocene ring. N-ferrocenoyl benzotriazole was reacted with alcohols in mild conditions to prepare ferrocenoyl esters in high purity and in good yield. The solid state structure of benzyl-1-ferrocenoate, 2f, has also been determined by X-ray crystallography. In the crystal structure, intermolecular C-H center dot center dot center dot O hydrogen bonds link the molecules into a two-dimensional network. The pi center dot center dot center dot pi contacts between the cyclopentadiene rings and cyclopentadiene and phenyl rings, [centroid-centroid distances = 3.296(1) and 3.750(1) angstrom] may further stabilize the structure. Two weak C-H center dot center dot center dot pi interactions are also found. (C) 2009 Elsevier B. V. All rights reserved.</dc:description>
  <dc:identifier>https://aperta.ulakbim.gov.trrecord/26957</dc:identifier>
  <dc:identifier>oai:zenodo.org:26957</dc:identifier>
  <dc:rights>info:eu-repo/semantics/openAccess</dc:rights>
  <dc:rights>http://www.opendefinition.org/licenses/cc-by</dc:rights>
  <dc:source>JOURNAL OF ORGANOMETALLIC CHEMISTRY 695(7) 1031-1034</dc:source>
  <dc:title>N-ferrocenoyl benzotriazole: A convenient tool for the synthesis of ferrocenoyl esters</dc:title>
  <dc:type>info:eu-repo/semantics/article</dc:type>
  <dc:type>publication-article</dc:type>
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