1 Ocak 2010 Dergi makalesi Açık Erişim

Hur, Deniz; Ekti, Sultan Funda; Dal, Hakan

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  <identifier identifierType="URL">https://aperta.ulakbim.gov.tr/record/26957</identifier>
  <creators>
    <creator>
      <creatorName>Hur, Deniz</creatorName>
      <givenName>Deniz</givenName>
      <familyName>Hur</familyName>
      <affiliation>Anadolu Univ, Fac Sci, Dept Chem, TR-26470 Eskisehir, Turkey</affiliation>
    </creator>
    <creator>
      <creatorName>Ekti, Sultan Funda</creatorName>
      <givenName>Sultan Funda</givenName>
      <familyName>Ekti</familyName>
      <affiliation>Anadolu Univ, Fac Sci, Dept Chem, TR-26470 Eskisehir, Turkey</affiliation>
    </creator>
    <creator>
      <creatorName>Dal, Hakan</creatorName>
      <givenName>Hakan</givenName>
      <familyName>Dal</familyName>
      <affiliation>Anadolu Univ, Fac Sci, Dept Chem, TR-26470 Eskisehir, Turkey</affiliation>
    </creator>
  </creators>
  <titles>
    <title>N-Ferrocenoyl Benzotriazole: A Convenient Tool For The Synthesis Of Ferrocenoyl Esters</title>
  </titles>
  <publisher>Aperta</publisher>
  <publicationYear>2010</publicationYear>
  <dates>
    <date dateType="Issued">2010-01-01</date>
  </dates>
  <resourceType resourceTypeGeneral="Text">Journal article</resourceType>
  <alternateIdentifiers>
    <alternateIdentifier alternateIdentifierType="url">https://aperta.ulakbim.gov.tr/record/26957</alternateIdentifier>
  </alternateIdentifiers>
  <relatedIdentifiers>
    <relatedIdentifier relatedIdentifierType="DOI" relationType="IsIdenticalTo">10.1016/j.jorganchem.2009.11.015</relatedIdentifier>
  </relatedIdentifiers>
  <rightsList>
    <rights rightsURI="http://www.opendefinition.org/licenses/cc-by">Creative Commons Attribution</rights>
    <rights rightsURI="info:eu-repo/semantics/openAccess">Open Access</rights>
  </rightsList>
  <descriptions>
    <description descriptionType="Abstract">A new synthesis methodology has been presented for the preparation of the ferrocenoyl esters. Ferrocene carboxylic acid was derivatized using direct 1H-benzotriazole/SOCl2 methodology to prepare N-ferrocenoyl benzotriazole as a convenient tool for the functionalization of ferrocene ring. N-ferrocenoyl benzotriazole was reacted with alcohols in mild conditions to prepare ferrocenoyl esters in high purity and in good yield. The solid state structure of benzyl-1-ferrocenoate, 2f, has also been determined by X-ray crystallography. In the crystal structure, intermolecular C-H center dot center dot center dot O hydrogen bonds link the molecules into a two-dimensional network. The pi center dot center dot center dot pi contacts between the cyclopentadiene rings and cyclopentadiene and phenyl rings, [centroid-centroid distances = 3.296(1) and 3.750(1) angstrom] may further stabilize the structure. Two weak C-H center dot center dot center dot pi interactions are also found. (C) 2009 Elsevier B. V. All rights reserved.</description>
  </descriptions>
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