1 Ocak 2010 Dergi makalesi Açık Erişim

Hur, Deniz; Ekti, Sultan Funda; Dal, Hakan

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{
  "@context": "https://schema.org/", 
  "@id": 26957, 
  "@type": "ScholarlyArticle", 
  "creator": [
    {
      "@type": "Person", 
      "affiliation": "Anadolu Univ, Fac Sci, Dept Chem, TR-26470 Eskisehir, Turkey", 
      "name": "Hur, Deniz"
    }, 
    {
      "@type": "Person", 
      "affiliation": "Anadolu Univ, Fac Sci, Dept Chem, TR-26470 Eskisehir, Turkey", 
      "name": "Ekti, Sultan Funda"
    }, 
    {
      "@type": "Person", 
      "affiliation": "Anadolu Univ, Fac Sci, Dept Chem, TR-26470 Eskisehir, Turkey", 
      "name": "Dal, Hakan"
    }
  ], 
  "datePublished": "2010-01-01", 
  "description": "A new synthesis methodology has been presented for the preparation of the ferrocenoyl esters. Ferrocene carboxylic acid was derivatized using direct 1H-benzotriazole/SOCl2 methodology to prepare N-ferrocenoyl benzotriazole as a convenient tool for the functionalization of ferrocene ring. N-ferrocenoyl benzotriazole was reacted with alcohols in mild conditions to prepare ferrocenoyl esters in high purity and in good yield. The solid state structure of benzyl-1-ferrocenoate, 2f, has also been determined by X-ray crystallography. In the crystal structure, intermolecular C-H center dot center dot center dot O hydrogen bonds link the molecules into a two-dimensional network. The pi center dot center dot center dot pi contacts between the cyclopentadiene rings and cyclopentadiene and phenyl rings, [centroid-centroid distances = 3.296(1) and 3.750(1) angstrom] may further stabilize the structure. Two weak C-H center dot center dot center dot pi interactions are also found. (C) 2009 Elsevier B. V. All rights reserved.", 
  "headline": "N-ferrocenoyl benzotriazole: A convenient tool for the synthesis of ferrocenoyl esters", 
  "identifier": 26957, 
  "image": "https://aperta.ulakbim.gov.tr/static/img/logo/aperta_logo_with_icon.svg", 
  "license": "http://www.opendefinition.org/licenses/cc-by", 
  "name": "N-ferrocenoyl benzotriazole: A convenient tool for the synthesis of ferrocenoyl esters", 
  "url": "https://aperta.ulakbim.gov.tr/record/26957"
}