1 Ocak 2010 Dergi makalesi Açık Erişim

Hur, Deniz; Ekti, Sultan Funda; Dal, Hakan

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      {
        "affiliation": "Anadolu Univ, Fac Sci, Dept Chem, TR-26470 Eskisehir, Turkey", 
        "name": "Hur, Deniz"
      }, 
      {
        "affiliation": "Anadolu Univ, Fac Sci, Dept Chem, TR-26470 Eskisehir, Turkey", 
        "name": "Ekti, Sultan Funda"
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      {
        "affiliation": "Anadolu Univ, Fac Sci, Dept Chem, TR-26470 Eskisehir, Turkey", 
        "name": "Dal, Hakan"
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    "description": "A new synthesis methodology has been presented for the preparation of the ferrocenoyl esters. Ferrocene carboxylic acid was derivatized using direct 1H-benzotriazole/SOCl2 methodology to prepare N-ferrocenoyl benzotriazole as a convenient tool for the functionalization of ferrocene ring. N-ferrocenoyl benzotriazole was reacted with alcohols in mild conditions to prepare ferrocenoyl esters in high purity and in good yield. The solid state structure of benzyl-1-ferrocenoate, 2f, has also been determined by X-ray crystallography. In the crystal structure, intermolecular C-H center dot center dot center dot O hydrogen bonds link the molecules into a two-dimensional network. The pi center dot center dot center dot pi contacts between the cyclopentadiene rings and cyclopentadiene and phenyl rings, [centroid-centroid distances = 3.296(1) and 3.750(1) angstrom] may further stabilize the structure. Two weak C-H center dot center dot center dot pi interactions are also found. (C) 2009 Elsevier B. V. All rights reserved.", 
    "doi": "10.1016/j.jorganchem.2009.11.015", 
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    "journal": {
      "issue": "7", 
      "pages": "1031-1034", 
      "title": "JOURNAL OF ORGANOMETALLIC CHEMISTRY", 
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    "title": "N-ferrocenoyl benzotriazole: A convenient tool for the synthesis of ferrocenoyl esters"
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