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Trace nickel determination in seawater matrix using combination of dispersive liquid-liquid microextraction and triethylamine-assisted Mg(OH)<sub>2</sub> method

Kublay, Irem Zehra; Kocoglu, Elif Seda; Oflu, Sude; Arvas, Busra; Yolacan, Cigdem; Bakirdere, Sezgin


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        "affiliation": "Yildiz Tech Univ, Fac Art & Sci, Chem Dept, TR-34220 Istanbul, Turkiye", 
        "name": "Kublay, Irem Zehra"
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      {
        "affiliation": "Yildiz Tech Univ, Cent Res Lab, TR-34220 Istanbul, Turkiye", 
        "name": "Kocoglu, Elif Seda"
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      {
        "affiliation": "Yildiz Tech Univ, Fac Art & Sci, Chem Dept, TR-34220 Istanbul, Turkiye", 
        "name": "Oflu, Sude"
      }, 
      {
        "affiliation": "Yildiz Tech Univ, Fac Art & Sci, Chem Dept, TR-34220 Istanbul, Turkiye", 
        "name": "Arvas, Busra"
      }, 
      {
        "affiliation": "Yildiz Tech Univ, Fac Art & Sci, Chem Dept, TR-34220 Istanbul, Turkiye", 
        "name": "Yolacan, Cigdem"
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      {
        "name": "Bakirdere, Sezgin"
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    "description": "<p>In order to eliminate the effects of seawater matrix on the precise/accurate determination of elements, new and efficient analytical procedure requires. In this study, co-precipitation method based on the triethylamine (TEA)-assisted Mg(OH)(2) was performed to eliminate side-effects of seawater medium on the determination with flame atomic absorption spectrometry (FAAS) prior to the preconcentration of nickel by an optimized dispersive liquid-liquid microextraction (DLLME) method. Under the optimum conditions of the presented method, the limit of detection and quantification (LOD, LOQ) values obtained for nickel were found as 16.1 and 53.8 &amp; mu;g kg(-1), respectively. Seawater samples collected from West Antarctic region were used for real sample applications to check the accuracy and applicability of developed method, and satisfying recovery results (86-97%) were obtained. In addition to this, the digital image-based colorimetric detection system and the UV-Vis system were applied to confirm the applicability of the developed DLLME-FAAS method in other analytical systems.</p>", 
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      "issue": "7", 
      "pages": "10", 
      "title": "ENVIRONMENTAL MONITORING AND ASSESSMENT", 
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    "title": "Trace nickel determination in seawater matrix using combination of dispersive liquid-liquid microextraction and triethylamine-assisted Mg(OH)<sub>2</sub> method"
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