Dergi makalesi Açık Erişim
Nawaz, Zahid; Gurbuz, Nevin; Zafar, Muhammad Naveed; Ozdemir, Namik; Habib, Uzma; Jan, Kalsoom; Ozdemir, Ismail
<?xml version='1.0' encoding='utf-8'?> <oai_dc:dc xmlns:dc="http://purl.org/dc/elements/1.1/" xmlns:oai_dc="http://www.openarchives.org/OAI/2.0/oai_dc/" xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance" xsi:schemaLocation="http://www.openarchives.org/OAI/2.0/oai_dc/ http://www.openarchives.org/OAI/2.0/oai_dc.xsd"> <dc:creator>Nawaz, Zahid</dc:creator> <dc:creator>Gurbuz, Nevin</dc:creator> <dc:creator>Zafar, Muhammad Naveed</dc:creator> <dc:creator>Ozdemir, Namik</dc:creator> <dc:creator>Habib, Uzma</dc:creator> <dc:creator>Jan, Kalsoom</dc:creator> <dc:creator>Ozdemir, Ismail</dc:creator> <dc:date>2021-01-01</dc:date> <dc:description>The goal of our research is to synthesis homogeneous catalysts, for which we take start from two novel precursors of 1-(3-methyloxetane-3-yl)benzimidazole and 5,6-dimethyl-1-((3-methyloxetane3-yl)benzimidazole. A series of ligands containing 1,3-disubstituted benzimidazolium salts were synthesized from the corresponding precursors to form N-heterocyclic carbene (NHC) ligands. Furthermore, four new Pd(NHC)-PEPPSI type complexes were synthesized from these ligands. The structure elucidation of all the synthesized ligands, and complexes was confirmed by various spectroscopic techniques such as NMR, FT-IR. The compounds 1b, 2b, 3a, 3d were confirmed by the X-ray technique. All these complexes were found significantly active as catalysts toward the C-C cross-coupling reaction. (c) 2021 Elsevier B.V. All rights reserved.</dc:description> <dc:identifier>https://aperta.ulakbim.gov.trrecord/238426</dc:identifier> <dc:identifier>oai:aperta.ulakbim.gov.tr:238426</dc:identifier> <dc:rights>info:eu-repo/semantics/openAccess</dc:rights> <dc:rights>http://www.opendefinition.org/licenses/cc-by</dc:rights> <dc:source>JOURNAL OF MOLECULAR STRUCTURE 1243</dc:source> <dc:title>Synthesis of new Pd(NHC)-PEPPSI type complexes as catalysts toward C-C cross-coupling reactions</dc:title> <dc:type>info:eu-repo/semantics/article</dc:type> <dc:type>publication-article</dc:type> </oai_dc:dc>
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