Dergi makalesi Açık Erişim

Synthesis of new Pd(NHC)-PEPPSI type complexes as catalysts toward C-C cross-coupling reactions

Nawaz, Zahid; Gurbuz, Nevin; Zafar, Muhammad Naveed; Ozdemir, Namik; Habib, Uzma; Jan, Kalsoom; Ozdemir, Ismail


JSON

{
  "conceptrecid": "238425", 
  "created": "2022-10-07T10:13:49.812226+00:00", 
  "doi": "10.1016/j.molstruc.2021.130883", 
  "files": [
    {
      "bucket": "b28ac357-96fb-493b-93ed-257a769889c7", 
      "checksum": "md5:6fae479d4ef37dd57aa2022c4f4e03f3", 
      "key": "bib-1fa5b7d7-a2bb-4503-825a-1bfb7bac2858.txt", 
      "links": {
        "self": "https://aperta.ulakbim.gov.tr/api/files/b28ac357-96fb-493b-93ed-257a769889c7/bib-1fa5b7d7-a2bb-4503-825a-1bfb7bac2858.txt"
      }, 
      "size": 228, 
      "type": "txt"
    }
  ], 
  "id": 238426, 
  "links": {
    "badge": "https://aperta.ulakbim.gov.tr/badge/doi/10.1016/j.molstruc.2021.130883.svg", 
    "bucket": "https://aperta.ulakbim.gov.tr/api/files/b28ac357-96fb-493b-93ed-257a769889c7", 
    "doi": "https://doi.org/10.1016/j.molstruc.2021.130883", 
    "html": "https://aperta.ulakbim.gov.tr/record/238426", 
    "latest": "https://aperta.ulakbim.gov.tr/api/records/238426", 
    "latest_html": "https://aperta.ulakbim.gov.tr/record/238426"
  }, 
  "metadata": {
    "access_right": "open", 
    "access_right_category": "success", 
    "communities": [
      {
        "id": "tubitak-destekli-proje-yayinlari"
      }
    ], 
    "creators": [
      {
        "name": "Nawaz, Zahid"
      }, 
      {
        "name": "Gurbuz, Nevin"
      }, 
      {
        "affiliation": "Quaid I Azam Univ, Dept Chem, Islamabad 45320, Pakistan", 
        "name": "Zafar, Muhammad Naveed"
      }, 
      {
        "affiliation": "Ondokuz Mayis Univ, Fac Educ, Dept Math & Sci Educ, TR-55139 Samsun, Turkey", 
        "name": "Ozdemir, Namik"
      }, 
      {
        "affiliation": "Natl Univ Sci & Technol, Res Ctr Modelling & Simulat, Islamabad 4400, Pakistan", 
        "name": "Habib, Uzma"
      }, 
      {
        "affiliation": "Natl Univ Sci & Technol, Res Ctr Modelling & Simulat, Islamabad 4400, Pakistan", 
        "name": "Jan, Kalsoom"
      }, 
      {
        "name": "Ozdemir, Ismail"
      }
    ], 
    "description": "The goal of our research is to synthesis homogeneous catalysts, for which we take start from two novel precursors of 1-(3-methyloxetane-3-yl)benzimidazole and 5,6-dimethyl-1-((3-methyloxetane3-yl)benzimidazole. A series of ligands containing 1,3-disubstituted benzimidazolium salts were synthesized from the corresponding precursors to form N-heterocyclic carbene (NHC) ligands. Furthermore, four new Pd(NHC)-PEPPSI type complexes were synthesized from these ligands. The structure elucidation of all the synthesized ligands, and complexes was confirmed by various spectroscopic techniques such as NMR, FT-IR. The compounds 1b, 2b, 3a, 3d were confirmed by the X-ray technique. All these complexes were found significantly active as catalysts toward the C-C cross-coupling reaction. (c) 2021 Elsevier B.V. All rights reserved.", 
    "doi": "10.1016/j.molstruc.2021.130883", 
    "has_grant": false, 
    "journal": {
      "title": "JOURNAL OF MOLECULAR STRUCTURE", 
      "volume": "1243"
    }, 
    "license": {
      "id": "cc-by"
    }, 
    "publication_date": "2021-01-01", 
    "relations": {
      "version": [
        {
          "count": 1, 
          "index": 0, 
          "is_last": true, 
          "last_child": {
            "pid_type": "recid", 
            "pid_value": "238426"
          }, 
          "parent": {
            "pid_type": "recid", 
            "pid_value": "238425"
          }
        }
      ]
    }, 
    "resource_type": {
      "subtype": "article", 
      "title": "Dergi makalesi", 
      "type": "publication"
    }, 
    "science_branches": [
      "Di\u011fer"
    ], 
    "title": "Synthesis of new Pd(NHC)-PEPPSI type complexes as catalysts toward C-C cross-coupling reactions"
  }, 
  "owners": [
    1
  ], 
  "revision": 1, 
  "stats": {
    "downloads": 6.0, 
    "unique_downloads": 6.0, 
    "unique_views": 14.0, 
    "version_downloads": 6.0, 
    "version_unique_downloads": 6.0, 
    "version_unique_views": 14.0, 
    "version_views": 15.0, 
    "version_volume": 1368.0, 
    "views": 15.0, 
    "volume": 1368.0
  }, 
  "updated": "2022-10-07T10:13:49.864761+00:00"
}
15
6
görüntülenme
indirilme
Görüntülenme 15
İndirme 6
Veri hacmi 1.4 kB
Tekil görüntülenme 14
Tekil indirme 6

Alıntı yap