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Synthesis of new Pd(NHC)-PEPPSI type complexes as catalysts toward C-C cross-coupling reactions

Nawaz, Zahid; Gurbuz, Nevin; Zafar, Muhammad Naveed; Ozdemir, Namik; Habib, Uzma; Jan, Kalsoom; Ozdemir, Ismail


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{
  "@context": "https://schema.org/", 
  "@id": 238426, 
  "@type": "ScholarlyArticle", 
  "creator": [
    {
      "@type": "Person", 
      "name": "Nawaz, Zahid"
    }, 
    {
      "@type": "Person", 
      "name": "Gurbuz, Nevin"
    }, 
    {
      "@type": "Person", 
      "affiliation": "Quaid I Azam Univ, Dept Chem, Islamabad 45320, Pakistan", 
      "name": "Zafar, Muhammad Naveed"
    }, 
    {
      "@type": "Person", 
      "affiliation": "Ondokuz Mayis Univ, Fac Educ, Dept Math & Sci Educ, TR-55139 Samsun, Turkey", 
      "name": "Ozdemir, Namik"
    }, 
    {
      "@type": "Person", 
      "affiliation": "Natl Univ Sci & Technol, Res Ctr Modelling & Simulat, Islamabad 4400, Pakistan", 
      "name": "Habib, Uzma"
    }, 
    {
      "@type": "Person", 
      "affiliation": "Natl Univ Sci & Technol, Res Ctr Modelling & Simulat, Islamabad 4400, Pakistan", 
      "name": "Jan, Kalsoom"
    }, 
    {
      "@type": "Person", 
      "name": "Ozdemir, Ismail"
    }
  ], 
  "datePublished": "2021-01-01", 
  "description": "The goal of our research is to synthesis homogeneous catalysts, for which we take start from two novel precursors of 1-(3-methyloxetane-3-yl)benzimidazole and 5,6-dimethyl-1-((3-methyloxetane3-yl)benzimidazole. A series of ligands containing 1,3-disubstituted benzimidazolium salts were synthesized from the corresponding precursors to form N-heterocyclic carbene (NHC) ligands. Furthermore, four new Pd(NHC)-PEPPSI type complexes were synthesized from these ligands. The structure elucidation of all the synthesized ligands, and complexes was confirmed by various spectroscopic techniques such as NMR, FT-IR. The compounds 1b, 2b, 3a, 3d were confirmed by the X-ray technique. All these complexes were found significantly active as catalysts toward the C-C cross-coupling reaction. (c) 2021 Elsevier B.V. All rights reserved.", 
  "headline": "Synthesis of new Pd(NHC)-PEPPSI type complexes as catalysts toward C-C cross-coupling reactions", 
  "identifier": 238426, 
  "image": "https://aperta.ulakbim.gov.tr/static/img/logo/aperta_logo_with_icon.svg", 
  "license": "http://www.opendefinition.org/licenses/cc-by", 
  "name": "Synthesis of new Pd(NHC)-PEPPSI type complexes as catalysts toward C-C cross-coupling reactions", 
  "url": "https://aperta.ulakbim.gov.tr/record/238426"
}
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