Dergi makalesi Açık Erişim
Nawaz, Zahid; Gurbuz, Nevin; Zafar, Muhammad Naveed; Ozdemir, Namik; Habib, Uzma; Jan, Kalsoom; Ozdemir, Ismail
{ "@context": "https://schema.org/", "@id": 238426, "@type": "ScholarlyArticle", "creator": [ { "@type": "Person", "name": "Nawaz, Zahid" }, { "@type": "Person", "name": "Gurbuz, Nevin" }, { "@type": "Person", "affiliation": "Quaid I Azam Univ, Dept Chem, Islamabad 45320, Pakistan", "name": "Zafar, Muhammad Naveed" }, { "@type": "Person", "affiliation": "Ondokuz Mayis Univ, Fac Educ, Dept Math & Sci Educ, TR-55139 Samsun, Turkey", "name": "Ozdemir, Namik" }, { "@type": "Person", "affiliation": "Natl Univ Sci & Technol, Res Ctr Modelling & Simulat, Islamabad 4400, Pakistan", "name": "Habib, Uzma" }, { "@type": "Person", "affiliation": "Natl Univ Sci & Technol, Res Ctr Modelling & Simulat, Islamabad 4400, Pakistan", "name": "Jan, Kalsoom" }, { "@type": "Person", "name": "Ozdemir, Ismail" } ], "datePublished": "2021-01-01", "description": "The goal of our research is to synthesis homogeneous catalysts, for which we take start from two novel precursors of 1-(3-methyloxetane-3-yl)benzimidazole and 5,6-dimethyl-1-((3-methyloxetane3-yl)benzimidazole. A series of ligands containing 1,3-disubstituted benzimidazolium salts were synthesized from the corresponding precursors to form N-heterocyclic carbene (NHC) ligands. Furthermore, four new Pd(NHC)-PEPPSI type complexes were synthesized from these ligands. The structure elucidation of all the synthesized ligands, and complexes was confirmed by various spectroscopic techniques such as NMR, FT-IR. The compounds 1b, 2b, 3a, 3d were confirmed by the X-ray technique. All these complexes were found significantly active as catalysts toward the C-C cross-coupling reaction. (c) 2021 Elsevier B.V. All rights reserved.", "headline": "Synthesis of new Pd(NHC)-PEPPSI type complexes as catalysts toward C-C cross-coupling reactions", "identifier": 238426, "image": "https://aperta.ulakbim.gov.tr/static/img/logo/aperta_logo_with_icon.svg", "license": "http://www.opendefinition.org/licenses/cc-by", "name": "Synthesis of new Pd(NHC)-PEPPSI type complexes as catalysts toward C-C cross-coupling reactions", "url": "https://aperta.ulakbim.gov.tr/record/238426" }
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