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Synthesis of new Pd(NHC)-PEPPSI type complexes as catalysts toward C-C cross-coupling reactions

Nawaz, Zahid; Gurbuz, Nevin; Zafar, Muhammad Naveed; Ozdemir, Namik; Habib, Uzma; Jan, Kalsoom; Ozdemir, Ismail


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  <identifier identifierType="URL">https://aperta.ulakbim.gov.tr/record/238426</identifier>
  <creators>
    <creator>
      <creatorName>Nawaz, Zahid</creatorName>
      <givenName>Zahid</givenName>
      <familyName>Nawaz</familyName>
    </creator>
    <creator>
      <creatorName>Gurbuz, Nevin</creatorName>
      <givenName>Nevin</givenName>
      <familyName>Gurbuz</familyName>
    </creator>
    <creator>
      <creatorName>Zafar, Muhammad Naveed</creatorName>
      <givenName>Muhammad Naveed</givenName>
      <familyName>Zafar</familyName>
      <affiliation>Quaid I Azam Univ, Dept Chem, Islamabad 45320, Pakistan</affiliation>
    </creator>
    <creator>
      <creatorName>Ozdemir, Namik</creatorName>
      <givenName>Namik</givenName>
      <familyName>Ozdemir</familyName>
      <affiliation>Ondokuz Mayis Univ, Fac Educ, Dept Math &amp; Sci Educ, TR-55139 Samsun, Turkey</affiliation>
    </creator>
    <creator>
      <creatorName>Habib, Uzma</creatorName>
      <givenName>Uzma</givenName>
      <familyName>Habib</familyName>
      <affiliation>Natl Univ Sci &amp; Technol, Res Ctr Modelling &amp; Simulat, Islamabad 4400, Pakistan</affiliation>
    </creator>
    <creator>
      <creatorName>Jan, Kalsoom</creatorName>
      <givenName>Kalsoom</givenName>
      <familyName>Jan</familyName>
      <affiliation>Natl Univ Sci &amp; Technol, Res Ctr Modelling &amp; Simulat, Islamabad 4400, Pakistan</affiliation>
    </creator>
    <creator>
      <creatorName>Ozdemir, Ismail</creatorName>
      <givenName>Ismail</givenName>
      <familyName>Ozdemir</familyName>
    </creator>
  </creators>
  <titles>
    <title>Synthesis Of New Pd(Nhc)-Peppsi Type Complexes As Catalysts Toward C-C Cross-Coupling Reactions</title>
  </titles>
  <publisher>Aperta</publisher>
  <publicationYear>2021</publicationYear>
  <dates>
    <date dateType="Issued">2021-01-01</date>
  </dates>
  <resourceType resourceTypeGeneral="Text">Journal article</resourceType>
  <alternateIdentifiers>
    <alternateIdentifier alternateIdentifierType="url">https://aperta.ulakbim.gov.tr/record/238426</alternateIdentifier>
  </alternateIdentifiers>
  <relatedIdentifiers>
    <relatedIdentifier relatedIdentifierType="DOI" relationType="IsIdenticalTo">10.1016/j.molstruc.2021.130883</relatedIdentifier>
  </relatedIdentifiers>
  <rightsList>
    <rights rightsURI="http://www.opendefinition.org/licenses/cc-by">Creative Commons Attribution</rights>
    <rights rightsURI="info:eu-repo/semantics/openAccess">Open Access</rights>
  </rightsList>
  <descriptions>
    <description descriptionType="Abstract">The goal of our research is to synthesis homogeneous catalysts, for which we take start from two novel precursors of 1-(3-methyloxetane-3-yl)benzimidazole and 5,6-dimethyl-1-((3-methyloxetane3-yl)benzimidazole. A series of ligands containing 1,3-disubstituted benzimidazolium salts were synthesized from the corresponding precursors to form N-heterocyclic carbene (NHC) ligands. Furthermore, four new Pd(NHC)-PEPPSI type complexes were synthesized from these ligands. The structure elucidation of all the synthesized ligands, and complexes was confirmed by various spectroscopic techniques such as NMR, FT-IR. The compounds 1b, 2b, 3a, 3d were confirmed by the X-ray technique. All these complexes were found significantly active as catalysts toward the C-C cross-coupling reaction. (c) 2021 Elsevier B.V. All rights reserved.</description>
  </descriptions>
</resource>
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