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Synthesis of alpha-Alkylated Ketones via Selective Epoxide Opening/Alkylation Reactions with Primary Alcohols

Genc, Sertac; Gulcemal, Suleyman; Gunnaz, Salih; Cetinkaya, Bekir; Gulcemal, Derya


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  <dc:creator>Genc, Sertac</dc:creator>
  <dc:creator>Gulcemal, Suleyman</dc:creator>
  <dc:creator>Gunnaz, Salih</dc:creator>
  <dc:creator>Cetinkaya, Bekir</dc:creator>
  <dc:creator>Gulcemal, Derya</dc:creator>
  <dc:date>2021-01-01</dc:date>
  <dc:description>A new method for converting terminal epoxides and primary alcohols into alpha-alkylated ketones under borrowing hydrogen conditions is reported. The procedure involves a one-pot epoxide ring opening and alkylation via primary alcohols in the presence of an N-heterocyclic carbene iridium(I) catalyst, under aerobic conditions, with water as the side product.</dc:description>
  <dc:identifier>https://aperta.ulakbim.gov.trrecord/234854</dc:identifier>
  <dc:identifier>oai:aperta.ulakbim.gov.tr:234854</dc:identifier>
  <dc:rights>info:eu-repo/semantics/openAccess</dc:rights>
  <dc:rights>http://www.opendefinition.org/licenses/cc-by</dc:rights>
  <dc:source>ORGANIC LETTERS 23(13) 5229-5234</dc:source>
  <dc:title>Synthesis of alpha-Alkylated Ketones via Selective Epoxide Opening/Alkylation Reactions with Primary Alcohols</dc:title>
  <dc:type>info:eu-repo/semantics/article</dc:type>
  <dc:type>publication-article</dc:type>
</oai_dc:dc>
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