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Synthesis of alpha-Alkylated Ketones via Selective Epoxide Opening/Alkylation Reactions with Primary Alcohols

Genc, Sertac; Gulcemal, Suleyman; Gunnaz, Salih; Cetinkaya, Bekir; Gulcemal, Derya


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{
  "@context": "https://schema.org/", 
  "@id": 234854, 
  "@type": "ScholarlyArticle", 
  "creator": [
    {
      "@type": "Person", 
      "affiliation": "Ege Univ, Chem Dept, TR-35100 Izmir, Turkey", 
      "name": "Genc, Sertac"
    }, 
    {
      "@type": "Person", 
      "affiliation": "Ege Univ, Chem Dept, TR-35100 Izmir, Turkey", 
      "name": "Gulcemal, Suleyman"
    }, 
    {
      "@type": "Person", 
      "affiliation": "Ege Univ, Chem Dept, TR-35100 Izmir, Turkey", 
      "name": "Gunnaz, Salih"
    }, 
    {
      "@type": "Person", 
      "affiliation": "Ege Univ, Chem Dept, TR-35100 Izmir, Turkey", 
      "name": "Cetinkaya, Bekir"
    }, 
    {
      "@type": "Person", 
      "affiliation": "Ege Univ, Chem Dept, TR-35100 Izmir, Turkey", 
      "name": "Gulcemal, Derya"
    }
  ], 
  "datePublished": "2021-01-01", 
  "description": "A new method for converting terminal epoxides and primary alcohols into alpha-alkylated ketones under borrowing hydrogen conditions is reported. The procedure involves a one-pot epoxide ring opening and alkylation via primary alcohols in the presence of an N-heterocyclic carbene iridium(I) catalyst, under aerobic conditions, with water as the side product.", 
  "headline": "Synthesis of alpha-Alkylated Ketones via Selective Epoxide Opening/Alkylation Reactions with Primary Alcohols", 
  "identifier": 234854, 
  "image": "https://aperta.ulakbim.gov.tr/static/img/logo/aperta_logo_with_icon.svg", 
  "license": "http://www.opendefinition.org/licenses/cc-by", 
  "name": "Synthesis of alpha-Alkylated Ketones via Selective Epoxide Opening/Alkylation Reactions with Primary Alcohols", 
  "url": "https://aperta.ulakbim.gov.tr/record/234854"
}
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