1 Ocak 2021 Dergi makalesi Açık Erişim

Genc, Sertac; Gulcemal, Suleyman; Gunnaz, Salih; Cetinkaya, Bekir; Gulcemal, Derya

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  <identifier identifierType="URL">https://aperta.ulakbim.gov.tr/record/234854</identifier>
  <creators>
    <creator>
      <creatorName>Genc, Sertac</creatorName>
      <givenName>Sertac</givenName>
      <familyName>Genc</familyName>
      <affiliation>Ege Univ, Chem Dept, TR-35100 Izmir, Turkey</affiliation>
    </creator>
    <creator>
      <creatorName>Gulcemal, Suleyman</creatorName>
      <givenName>Suleyman</givenName>
      <familyName>Gulcemal</familyName>
      <affiliation>Ege Univ, Chem Dept, TR-35100 Izmir, Turkey</affiliation>
    </creator>
    <creator>
      <creatorName>Gunnaz, Salih</creatorName>
      <givenName>Salih</givenName>
      <familyName>Gunnaz</familyName>
      <affiliation>Ege Univ, Chem Dept, TR-35100 Izmir, Turkey</affiliation>
    </creator>
    <creator>
      <creatorName>Cetinkaya, Bekir</creatorName>
      <givenName>Bekir</givenName>
      <familyName>Cetinkaya</familyName>
      <affiliation>Ege Univ, Chem Dept, TR-35100 Izmir, Turkey</affiliation>
    </creator>
    <creator>
      <creatorName>Gulcemal, Derya</creatorName>
      <givenName>Derya</givenName>
      <familyName>Gulcemal</familyName>
      <affiliation>Ege Univ, Chem Dept, TR-35100 Izmir, Turkey</affiliation>
    </creator>
  </creators>
  <titles>
    <title>Synthesis Of Alpha-Alkylated Ketones Via Selective Epoxide Opening/Alkylation Reactions With Primary Alcohols</title>
  </titles>
  <publisher>Aperta</publisher>
  <publicationYear>2021</publicationYear>
  <dates>
    <date dateType="Issued">2021-01-01</date>
  </dates>
  <resourceType resourceTypeGeneral="Text">Journal article</resourceType>
  <alternateIdentifiers>
    <alternateIdentifier alternateIdentifierType="url">https://aperta.ulakbim.gov.tr/record/234854</alternateIdentifier>
  </alternateIdentifiers>
  <relatedIdentifiers>
    <relatedIdentifier relatedIdentifierType="DOI" relationType="IsIdenticalTo">10.1021/acs.orglett.1c01765</relatedIdentifier>
  </relatedIdentifiers>
  <rightsList>
    <rights rightsURI="http://www.opendefinition.org/licenses/cc-by">Creative Commons Attribution</rights>
    <rights rightsURI="info:eu-repo/semantics/openAccess">Open Access</rights>
  </rightsList>
  <descriptions>
    <description descriptionType="Abstract">A new method for converting terminal epoxides and primary alcohols into alpha-alkylated ketones under borrowing hydrogen conditions is reported. The procedure involves a one-pot epoxide ring opening and alkylation via primary alcohols in the presence of an N-heterocyclic carbene iridium(I) catalyst, under aerobic conditions, with water as the side product.</description>
  </descriptions>
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