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Reactions of acyl phosphonates with organoaluminum reagents: a new method for the synthesis of secondary and tertiary alpha-hydroxy phosphonates

Seven, Ozlem; Polat-Cakir, Sidika; Hossain, Md. Shakhawoat; Emrullahoglu, Mustafa; Demir, Ayhan S.


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{
  "@context": "https://schema.org/", 
  "@id": 22931, 
  "@type": "ScholarlyArticle", 
  "creator": [
    {
      "@type": "Person", 
      "affiliation": "Middle E Tech Univ, Dept Chem, TR-06531 Ankara, Turkey", 
      "name": "Seven, Ozlem"
    }, 
    {
      "@type": "Person", 
      "name": "Polat-Cakir, Sidika"
    }, 
    {
      "@type": "Person", 
      "affiliation": "Middle E Tech Univ, Dept Chem, TR-06531 Ankara, Turkey", 
      "name": "Hossain, Md. Shakhawoat"
    }, 
    {
      "@type": "Person", 
      "name": "Emrullahoglu, Mustafa"
    }, 
    {
      "@type": "Person", 
      "affiliation": "Middle E Tech Univ, Dept Chem, TR-06531 Ankara, Turkey", 
      "name": "Demir, Ayhan S."
    }
  ], 
  "datePublished": "2011-01-01", 
  "description": "The reactions of organoaluminum reagents (trimethylaluminum, triethylaluminum, etc.) with aryl and alkyl acyl phosphonates, which lead to the formation of alpha-hydroxy phosphonates in moderate to good yields, are reported. This method provides easy access to secondary and tertiary alpha-hydroxy phosphonates depending on the reaction conditions. The reactions of triethylaluminum with a series of acyl phosphonates at 0 degrees C gave the secondary alpha-hydroxy phosphonates, while at -100 degrees C they afford the tertiary alpha-hydroxy phosphonates. (C) 2011 Elsevier Ltd. All rights reserved.", 
  "headline": "Reactions of acyl phosphonates with organoaluminum reagents: a new method for the synthesis of secondary and tertiary alpha-hydroxy phosphonates", 
  "identifier": 22931, 
  "image": "https://aperta.ulakbim.gov.tr/static/img/logo/aperta_logo_with_icon.svg", 
  "license": "http://www.opendefinition.org/licenses/cc-by", 
  "name": "Reactions of acyl phosphonates with organoaluminum reagents: a new method for the synthesis of secondary and tertiary alpha-hydroxy phosphonates", 
  "url": "https://aperta.ulakbim.gov.tr/record/22931"
}
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