1 Ocak 2011 Dergi makalesi Açık Erişim

Seven, Ozlem; Polat-Cakir, Sidika; Hossain, Md. Shakhawoat; Emrullahoglu, Mustafa; Demir, Ayhan S.

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  <identifier identifierType="URL">https://aperta.ulakbim.gov.tr/record/22931</identifier>
  <creators>
    <creator>
      <creatorName>Seven, Ozlem</creatorName>
      <givenName>Ozlem</givenName>
      <familyName>Seven</familyName>
      <affiliation>Middle E Tech Univ, Dept Chem, TR-06531 Ankara, Turkey</affiliation>
    </creator>
    <creator>
      <creatorName>Polat-Cakir, Sidika</creatorName>
      <givenName>Sidika</givenName>
      <familyName>Polat-Cakir</familyName>
    </creator>
    <creator>
      <creatorName>Hossain, Md. Shakhawoat</creatorName>
      <givenName>Md. Shakhawoat</givenName>
      <familyName>Hossain</familyName>
      <affiliation>Middle E Tech Univ, Dept Chem, TR-06531 Ankara, Turkey</affiliation>
    </creator>
    <creator>
      <creatorName>Emrullahoglu, Mustafa</creatorName>
      <givenName>Mustafa</givenName>
      <familyName>Emrullahoglu</familyName>
    </creator>
    <creator>
      <creatorName>Demir, Ayhan S.</creatorName>
      <givenName>Ayhan S.</givenName>
      <familyName>Demir</familyName>
      <affiliation>Middle E Tech Univ, Dept Chem, TR-06531 Ankara, Turkey</affiliation>
    </creator>
  </creators>
  <titles>
    <title>Reactions Of Acyl Phosphonates With Organoaluminum Reagents: A New Method For The Synthesis Of Secondary And Tertiary Alpha-Hydroxy Phosphonates</title>
  </titles>
  <publisher>Aperta</publisher>
  <publicationYear>2011</publicationYear>
  <dates>
    <date dateType="Issued">2011-01-01</date>
  </dates>
  <resourceType resourceTypeGeneral="Text">Journal article</resourceType>
  <alternateIdentifiers>
    <alternateIdentifier alternateIdentifierType="url">https://aperta.ulakbim.gov.tr/record/22931</alternateIdentifier>
  </alternateIdentifiers>
  <relatedIdentifiers>
    <relatedIdentifier relatedIdentifierType="DOI" relationType="IsIdenticalTo">10.1016/j.tet.2011.03.036</relatedIdentifier>
  </relatedIdentifiers>
  <rightsList>
    <rights rightsURI="http://www.opendefinition.org/licenses/cc-by">Creative Commons Attribution</rights>
    <rights rightsURI="info:eu-repo/semantics/openAccess">Open Access</rights>
  </rightsList>
  <descriptions>
    <description descriptionType="Abstract">The reactions of organoaluminum reagents (trimethylaluminum, triethylaluminum, etc.) with aryl and alkyl acyl phosphonates, which lead to the formation of alpha-hydroxy phosphonates in moderate to good yields, are reported. This method provides easy access to secondary and tertiary alpha-hydroxy phosphonates depending on the reaction conditions. The reactions of triethylaluminum with a series of acyl phosphonates at 0 degrees C gave the secondary alpha-hydroxy phosphonates, while at -100 degrees C they afford the tertiary alpha-hydroxy phosphonates. (C) 2011 Elsevier Ltd. All rights reserved.</description>
  </descriptions>
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