Dergi makalesi Açık Erişim
Seven, Ozlem; Polat-Cakir, Sidika; Hossain, Md. Shakhawoat; Emrullahoglu, Mustafa; Demir, Ayhan S.
{ "DOI": "10.1016/j.tet.2011.03.036", "abstract": "The reactions of organoaluminum reagents (trimethylaluminum, triethylaluminum, etc.) with aryl and alkyl acyl phosphonates, which lead to the formation of alpha-hydroxy phosphonates in moderate to good yields, are reported. This method provides easy access to secondary and tertiary alpha-hydroxy phosphonates depending on the reaction conditions. The reactions of triethylaluminum with a series of acyl phosphonates at 0 degrees C gave the secondary alpha-hydroxy phosphonates, while at -100 degrees C they afford the tertiary alpha-hydroxy phosphonates. (C) 2011 Elsevier Ltd. All rights reserved.", "author": [ { "family": "Seven", "given": " Ozlem" }, { "family": "Polat-Cakir", "given": " Sidika" }, { "family": "Hossain", "given": " Md. Shakhawoat" }, { "family": "Emrullahoglu", "given": " Mustafa" }, { "family": "Demir", "given": " Ayhan S." } ], "container_title": "TETRAHEDRON", "id": "22931", "issue": "19", "issued": { "date-parts": [ [ 2011, 1, 1 ] ] }, "page": "3464-3469", "title": "Reactions of acyl phosphonates with organoaluminum reagents: a new method for the synthesis of secondary and tertiary alpha-hydroxy phosphonates", "type": "article-journal", "volume": "67" }
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