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Novel cycloaurated gold(III) complexes and their effects on styrene polymerization

Hanhan, Murat Emre


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  <dc:creator>Hanhan, Murat Emre</dc:creator>
  <dc:date>2011-01-01</dc:date>
  <dc:description>Novel cycloaurated gold(III) complexes were prepared by using Schiff bases with different substituents. Effects of the synthesized gold(III) complexes and substituent groups on styrene polymerization were investigated. As a result of these investigations, it was observed that gold(III) complexes could not catalyze polymerization reaction without addition of a co-catalyst like NaBAr'(4) (Ar'=3,5-bis(trifluoromethyl) phenyl). All ligands and complexes were characterized by using H-1 nuclear magnetic resonance (NMR), C-13-NMR, LC-MS, elemental analysis and FT-IR techniques. The architecture of the polymer was determined as an atactic or sydiotactic polymer by using C-13-NMR and DSC techniques. Molecular weights of the polymers were analyzed by using gel permeation chromatogram (GPC).</dc:description>
  <dc:identifier>https://aperta.ulakbim.gov.trrecord/20519</dc:identifier>
  <dc:identifier>oai:zenodo.org:20519</dc:identifier>
  <dc:rights>info:eu-repo/semantics/openAccess</dc:rights>
  <dc:rights>http://www.opendefinition.org/licenses/cc-by</dc:rights>
  <dc:source>GOLD BULLETIN 44(1) 43-47</dc:source>
  <dc:title>Novel cycloaurated gold(III) complexes and their effects on styrene polymerization</dc:title>
  <dc:type>info:eu-repo/semantics/article</dc:type>
  <dc:type>publication-article</dc:type>
</oai_dc:dc>
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