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Novel cycloaurated gold(III) complexes and their effects on styrene polymerization

Hanhan, Murat Emre


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    "description": "Novel cycloaurated gold(III) complexes were prepared by using Schiff bases with different substituents. Effects of the synthesized gold(III) complexes and substituent groups on styrene polymerization were investigated. As a result of these investigations, it was observed that gold(III) complexes could not catalyze polymerization reaction without addition of a co-catalyst like NaBAr'(4) (Ar'=3,5-bis(trifluoromethyl) phenyl). All ligands and complexes were characterized by using H-1 nuclear magnetic resonance (NMR), C-13-NMR, LC-MS, elemental analysis and FT-IR techniques. The architecture of the polymer was determined as an atactic or sydiotactic polymer by using C-13-NMR and DSC techniques. Molecular weights of the polymers were analyzed by using gel permeation chromatogram (GPC).", 
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      "issue": "1", 
      "pages": "43-47", 
      "title": "GOLD BULLETIN", 
      "volume": "44"
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    "publication_date": "2011-01-01", 
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    "title": "Novel cycloaurated gold(III) complexes and their effects on styrene polymerization"
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