Dergi makalesi Açık Erişim
Hanhan, Murat Emre
{ "DOI": "10.1007/s13404-011-0006-9", "abstract": "Novel cycloaurated gold(III) complexes were prepared by using Schiff bases with different substituents. Effects of the synthesized gold(III) complexes and substituent groups on styrene polymerization were investigated. As a result of these investigations, it was observed that gold(III) complexes could not catalyze polymerization reaction without addition of a co-catalyst like NaBAr'(4) (Ar'=3,5-bis(trifluoromethyl) phenyl). All ligands and complexes were characterized by using H-1 nuclear magnetic resonance (NMR), C-13-NMR, LC-MS, elemental analysis and FT-IR techniques. The architecture of the polymer was determined as an atactic or sydiotactic polymer by using C-13-NMR and DSC techniques. Molecular weights of the polymers were analyzed by using gel permeation chromatogram (GPC).", "author": [ { "family": "Hanhan", "given": " Murat Emre" } ], "container_title": "GOLD BULLETIN", "id": "20519", "issue": "1", "issued": { "date-parts": [ [ 2011, 1, 1 ] ] }, "page": "43-47", "title": "Novel cycloaurated gold(III) complexes and their effects on styrene polymerization", "type": "article-journal", "volume": "44" }
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