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Novel cycloaurated gold(III) complexes and their effects on styrene polymerization

Hanhan, Murat Emre


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{
  "DOI": "10.1007/s13404-011-0006-9", 
  "abstract": "Novel cycloaurated gold(III) complexes were prepared by using Schiff bases with different substituents. Effects of the synthesized gold(III) complexes and substituent groups on styrene polymerization were investigated. As a result of these investigations, it was observed that gold(III) complexes could not catalyze polymerization reaction without addition of a co-catalyst like NaBAr'(4) (Ar'=3,5-bis(trifluoromethyl) phenyl). All ligands and complexes were characterized by using H-1 nuclear magnetic resonance (NMR), C-13-NMR, LC-MS, elemental analysis and FT-IR techniques. The architecture of the polymer was determined as an atactic or sydiotactic polymer by using C-13-NMR and DSC techniques. Molecular weights of the polymers were analyzed by using gel permeation chromatogram (GPC).", 
  "author": [
    {
      "family": "Hanhan", 
      "given": " Murat Emre"
    }
  ], 
  "container_title": "GOLD BULLETIN", 
  "id": "20519", 
  "issue": "1", 
  "issued": {
    "date-parts": [
      [
        2011, 
        1, 
        1
      ]
    ]
  }, 
  "page": "43-47", 
  "title": "Novel cycloaurated gold(III) complexes and their effects on styrene polymerization", 
  "type": "article-journal", 
  "volume": "44"
}
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